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Specific interactions in mixed electrolyte solutions from solubility measurements

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Abstract

The solubility of thallium I chloride in a wide range of dilute electrolyte solutions is interpreted using a new specific-interaction equation for activity coefficients. This equation is shown to be consistent with the solubility data, but the Guggenheim specific-interaction equation is not. The relation of interaction coefficients to ion association is discussed.

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Panckhurst, M.H., Macaskill, J.B. Specific interactions in mixed electrolyte solutions from solubility measurements. J Solution Chem 5, 483–490 (1976). https://doi.org/10.1007/BF00650465

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  • DOI: https://doi.org/10.1007/BF00650465

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