Skip to main content
SpringerLink
Log in

Calculation of Gurney parameters for aqueous tetraalkylammonium halides based on Friedman's cosphere-overlap model

  • Published:
Journal of Solution Chemistry Aims and scope Submit manuscript

Abstract

Recalculations of the Gurney free-energy parameters Aij based on the cosphereoverlap model of Friedman and co-workers have been made using more recent experimental data. Our procedure for calculation seems to be more systematic than those previously reported. The excess energy, entropy, and volume parameters (Eij, TSij, and Vij) were also recalculated for some aqueous tetraalkylammonium halides. In addition, the excess-heat-capacity parameters Cij are also reported here for the first time. These data are discussed briefly in terms of the structural implications.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. H. L. Friedman and P. S. Ramanathan,J. Phys. Chem. 74, 3756 (1970).

    Google Scholar 

  2. P. S. Ramanathan and H. L. Friedman,J. Chem. Phys. 54, 1086 (1971).

    Google Scholar 

  3. P. S. Ramanathan, C. V. Krishnan, and H. L. Friedman,J. Solution Chem. 1, 237 (1972).

    Google Scholar 

  4. H. L. Friedman, C. V. Krishnan, and C. Jolicoeur,Ann. N.Y. Acad. Sci. 204, 79 (1973).

    Google Scholar 

  5. W.-Y. Wen and S. Saito,J. Phys. Chem. 68, 2639 (1964).

    Google Scholar 

  6. A. S. Levine and S. Lindenbaum,J. Solution Chem. 2, 445 (1973).

    Google Scholar 

  7. R. A. Robinson and R. H. Stokes,Electrolyte Solutions (Butterworths, London, 1965), 2nd ed., p. 125.

    Google Scholar 

  8. J. P. Rupert, Ph. D. Thesis, University of Pittsburgh, 1969.

  9. J. C. Ku, Ph. D. Thesis, University of Pittsburgh, 1971.

  10. T. Kangvanvongsa, Ph. D. Thesis, Michigan Technological University, 1971.

  11. H. L. Friedman,J. Solution Chem. 1, 387 (1972).

    Google Scholar 

  12. H. L. Friedman,J. Solution Chem. 1, 413 (1972).

    Google Scholar 

  13. P. R. Philip and J. E. Desnoyers,J. Solution Chem. 1, 353 (1972).

    Google Scholar 

  14. H. L. Friedman, C. V. Krishnan, and L. P. Hwang, to be published inWater as Liquid and Solvent, Proceedings of the Marburg Symposium, July, 1973, W. Luck, ed. (Verlag Chemie, 1974).

  15. P. S. Ramanathan, C. V. Krishnan, and H. L. Friedman,J. Solution Chem. 1, 237 (1972), Figs. 6 and 9.

    Google Scholar 

  16. W.-Y. Wen,J. Solution Chem. 2, 253 (1973).

    Google Scholar 

Download references

Author information

Author notes

  1. William H. Streng

    Present address: Merrell-National Laboratories, Division of Richardson-Merrell Inc., 45215, Cincinatti, Ohio

Authors and Affiliations

  1. Department of Chemistry, Jeppson Laboratory, Clark University, 01610, Worcester, Massachusetts

    William H. Streng & Wen-Yang Wen

Authors
  1. William H. Streng
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Wen-Yang Wen
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Streng, W.H., Wen, WY. Calculation of Gurney parameters for aqueous tetraalkylammonium halides based on Friedman's cosphere-overlap model. J Solution Chem 3, 865–880 (1974). https://doi.org/10.1007/BF00647941

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00647941

Key Words

Search

Navigation