Abstract
Potentiometric, calorimetric, and dilatometric data on the ionization of several saturated dicarboxylic acids in water at 25°C are reported. A correlation is attempted between structure and thermodynamic evidences for the two dissociation stages of the diacids considered, in particular in terms of the propensity toward intramolecular hydrogen bond formation of some singly ionized species.
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Delben, F., Crescenzi, V. The ionization of aliphatic dicarboxylic acids in water. J Solution Chem 7, 597–604 (1978). https://doi.org/10.1007/BF00646037
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DOI: https://doi.org/10.1007/BF00646037