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Conductance study of some 1-1 electrolytes in dimethyl sulfoxide and hexamethylphosphoramide

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Abstract

Conductance measurements of 1-1 electrolytes were made in HMPT and DMSO at 25°C. The limiting conductances and the association constants were evaluated and discussed in terms of solvation. A great similarity is observed between these dipolar aprotic solvents. For sodium and potassium ions, the results can be explained in terms of classic ion-dipole interactions. For other ions such as tetraalkylammonium, tetraphenylboride, chlorate, and perchlorate, the solvation cosphere effects increase the mobilities and the short-range attractions between anions and cations.

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Authors and Affiliations

  1. Laboratoire de Chimie Organique Physique de l'Université Paris VII, 75005, Paris, France

    Charley Atlani

  2. Laboratoire d'Electrochimie de l'Université Paris VI, 75005, Paris, France

    Jean-Claude Justice

Authors
  1. Charley Atlani
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  2. Jean-Claude Justice
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Atlani, C., Justice, JC. Conductance study of some 1-1 electrolytes in dimethyl sulfoxide and hexamethylphosphoramide. J Solution Chem 4, 955–963 (1975). https://doi.org/10.1007/BF00645891

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  • DOI: https://doi.org/10.1007/BF00645891

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