Abstract
The diffusion coefficients in the ternary system NaCl (0.3 m)−NH4Cl (0.3 m)−H2O at 25° C have been measured. Some aspects of the diffusion equations for ternary systems are discussed within the range of applicability of the Gouy technique and based on the gravitational stability of free diffusion layers.
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References
A. Weissberger,Physical Methods of Chemistry, Vol. 1, Part IV (Wiley, New York, 1972).
G. Kegeles and L. J. Gosting,J. Am. Chem. Soc. 69, 2516 (1947).
L. J. Gosting, E. M. Hanson, G. Kegeles, and M. S. Morris,Rev. Sci. Instrum. 20, 209 (1949).
M. Brakke,Arch. Biochem. Biophys. 55, 175 (1955).
R. P. Wendt,J. Phys. Chem. 66, 1740 (1962).
Y. Oishi,J. Chem. Phys. 43, 1611 (1965).
V. Vitagliano, A. Zagari, R. Sartorio, and M. Corcione,J. Phys. Chem. 76, 2050 (1972).
H. Fujita and L. J. Gosting,J. Am. Chem. Soc. 78, 1099 (1956).
H. Fujita and L. J. Gosting,J. Phys. Chem. 64, 1256 (1960).
P. J. Dunlop and L. J. Gosting,J. Am. Chem. Soc. 77, 5238 (1955), footnote 19.
L. G. Longsworth,J. Am. Chem. Soc. 74, 4155 (1952).
L. G. Longsworth,J. Phys. Chem. 61, 244 (1957).
J. S. Philpot,Nature (London) 141, 283 (1938).
M. Bier,Electrophoresis (Academic Press,New York, 1959), p. 145.
P. J. Dunlop,J. Phys. Chem. 61, 994 (1957).
H. Kim,J. Phys. Chem. 74, 4577 (1970).
V. Vitagliano, R. Sartorio, and L. Costantino,J. Phys. Chem. 78, 2292 (1974).
A. Revzin,J. Phys. Chem. 76, 3419 (1972).
L. Gosting and M. S. Morris,J. Am. Chem. Soc. 71, 1998 (1949).
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Vitagliano, V., Sartorio, R., Spaduzzi, D. et al. Some comments on diffusion in ternary systems. J Solution Chem 6, 671–686 (1977). https://doi.org/10.1007/BF00645884
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DOI: https://doi.org/10.1007/BF00645884