Abstract
The formation constants of the LnSO +4 complexes are reported for La3+, Pr3+, Sm3+, Dy3+, Yb3+, and Lu3+ in D2O and for Sm3+ and Lu3+ in water at 25°C. Formation constants which were calculated from conductance data are identical with those obtained in H2O within the limits of the assumptions made in the mathematical analysis.
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References
P. M. Laughton and R. E. Robertson,Solute-Solvent Interactions, J. F. Coetzee and C. D. Ritchie, eds. (Marcel Dekker, New York, 1969), Chap. 7.
E. M. Arnett and D. R. McKelvey,Solute-Solvent Interactions, J. F. Coetzee and C. D. Ritchie, eds. (Marcel Dekker, New York, 1969), Chap. 6.
R. Gary, R. G. Bates, and R. A. Robinson,J. Phys. Chem. 69, 2750 (1965).
N. Sutin, J. K. Rowley, and R. W. Dodson,J. Phys. Chem. 65, 1248 (1961).
D. Bunn, F. S. Dainton, and S. Duckworth,Trans. Faraday Soc. 57, 1131 (1961).
D. L. McMasters, J. C. DiRaimondo, L. H. Jones, R. P. Lindley, and E. W. Zeltman,J. Phys. Chem. 66, 249 (1962).
D. P. Fay and N. Purdie,J. Phys. Chem. 73, 3462 (1969).
N. Purdie et al.Trans. Faraday Soc. 63, 2745 (1967).
J. Phys. Chem. 73, 544 (1969).
J. Phys. Chem. 74, 1160 (1970).
N. Purdieet al. with M. M. Farrow, submitted for publication.
F. H. Spedding and S. Jaffe,J. Am. Chem. Soc. 76, 882 (1954).
J. G. Mathieson and B. C. Conway,Anal. Chem. 44, 1517 (1972).
G. Jones and B. C. Bradshaw,J. Am. Chem. Soc. 55, 1780 (1933).
C. W. Davies,Ion Association (Butterworths Publishing Co., London, 1962), p. 16.
R. A. Robinson and R. H. Stokes,Electrolyte Solutions (Butterworths Publishing Co., London, 1959), 2nd ed., p. 143.
R. L. Kay and D. F. Evans,J. Phys. Chem. 70, 2325 (1966).
I. L. Jenkins and C. B. Monk,J. Am. Chem. Soc. 72, 2695 (1950).
C. F. Hale and F. H. Spedding,J. Phys. Chem. 76, 1887 (1972).
H. B. Silber,Chem. Commun. Chem. Soc. London, 731 (1971).
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Farrow, M.M., Purdie, N. The conductance of lanthanide (III) sulfate solutions in D2O. J Solution Chem 2, 503–511 (1973). https://doi.org/10.1007/BF00644877
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DOI: https://doi.org/10.1007/BF00644877