Skip to main content
SpringerLink
Log in

Synthesis and structure of diethyl 2-oxo-1-oxaspiro[4,5]decane-3,4-dicarboxylate

  • Published:
Chemistry of Heterocyclic Compounds Aims and scope

Abstract

Ethyl 1-oxaspiro[2,5]octane-2-carboxylate reacts with diethyl sodiomalonate in toluene to give diethyl 2-oxo-1-oxaspiro[4,5]decane-3,4-dicarboxylate, which on distillation under goes partial de-ethoxycarbonylation to give ethyl 2-oxo-1-oxaspiro[4,5]decane-4-carboxylate.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature Cited

  1. R. A. Kuroyan, A. I. Markosyan, A. P. Engoyan, and S. A. Vartanyan,Zh. Org. Khim.,19, 1947 (1983).

    Google Scholar 

  2. G. V. Chelintsev and E. D. Osetrova,Zh. Obshch. Khim.,7, 2373 (1937).

    Google Scholar 

  3. W. B. Schweizer and Y. D. Dunits,Helv. Chim. Acta,65, 1547 (1982).

    Google Scholar 

  4. G. Bocelli and M. F. Grenier-Loustalot,Acta Cryst.,B37, 2106 (1981).

    Google Scholar 

  5. R. T. Harlov and S. H. Simonsen,Acta Cryst.,B32, 2137 (1976).

    Google Scholar 

  6. F. H. Allen, O. Kennard, D. G. Watson, L. Brammer, A. G. Orpan, and R. Taylor,J. Chem. Soc., Perkin Trans. 2, 1 (1987).

    Google Scholar 

  7. V. M. Rodionov and T. S. Kiselev,Izv. Akad. Nauk SSSR, Ser. Khim., Otd. Khim. Nauk., No. 2, 278 (1952).

    Google Scholar 

  8. R. G. Gerr, A. I. Yanovskii, and Yu. T. Struchkov,Kristallografiya,28, 1029 (1983).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. A. L. Mndzhoyan Institute of Fine Organic Chemistry, Academy of Sciences of the ArmenianSSR, Erevan

    R. A. Kuroyan, S. A. Pogosyan, N. P. Grigoryan, M. S. Aleksanyan, A. A. Karapetyan, S. V. Lindeman & Y. T. Struchkov

Authors
  1. R. A. Kuroyan
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. S. A. Pogosyan
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. N. P. Grigoryan
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. M. S. Aleksanyan
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. A. A. Karapetyan
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. S. V. Lindeman
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. Y. T. Struchkov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 1, pp. 28–32, January, 1991.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kuroyan, R.A., Pogosyan, S.A., Grigoryan, N.P. et al. Synthesis and structure of diethyl 2-oxo-1-oxaspiro[4,5]decane-3,4-dicarboxylate. Chem Heterocycl Compd 27, 23–26 (1991). https://doi.org/10.1007/BF00633209

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00633209

Keywords

Search

Navigation