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New injection valves and their application in flow injection analysis

Neue Injektionsventile und ihre Anwendung in der Fließinjektionsanalyse

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Summary

Two variable volume injection valves, equipped with bypass loops, have been developed, primarily to circumvent problems with matrix effects in high sensitivity FIA.

The application of a dual channel valve for simultaneous analysis, zone sampling and merging zones techniques is discussed.

Examples for on-line dilutions up to several thousand-fold and the direct determination of calcium in Kjeldahl digests using the zone sampling approach and a study of the interference of ascorbic acid on the Griess reaction for nitrite are presented. The application of “chasing zones” techniques by coupling a simple single channel valve in a new way is proposed.

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References

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Möller, J. New injection valves and their application in flow injection analysis. Z. Anal. Chem. 329, 685–687 (1988). https://doi.org/10.1007/BF00624775

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  • DOI: https://doi.org/10.1007/BF00624775

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