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The infrared spectra of imidazole complexes of platinum(II) halides and nitrite

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Summary

The i.r. spectra (4000-90 cm−1) of the [Pt(Him)4]X2 complexes (Him = imidazole, X = Cl, Br or I) andcis- andtrans-[Pt(Him)2X2] (X = Cl, Br, I or NO2) and their D3-labelled analogues have been determined. The distinction between the ring and C-H (or N-H) modes of imidazole is based on the relative shifts which these bands undergo on D3-labelling. Assignments, based on the effects of imidazole deuteriation and halide substitution, are provided for the v(Pt-Him) and v(Pt-X) modes.

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Authors and Affiliations

  1. Department of Inorganic Chemistry, University of Cape Town, 7700, Rondebosch, South Africa

    Steven J. Archer, Thomas P. E. Auf der Heyde, Gary A. Foulds & David A. Thornton

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  1. Steven J. Archer
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  2. Thomas P. E. Auf der Heyde
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  3. Gary A. Foulds
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  4. David A. Thornton
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Archer, S.J., Auf der Heyde, T.P.E., Foulds, G.A. et al. The infrared spectra of imidazole complexes of platinum(II) halides and nitrite. Transition Met Chem 7, 59–62 (1982). https://doi.org/10.1007/BF00623811

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  • DOI: https://doi.org/10.1007/BF00623811

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