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Crystal structure oftrans-(benzyl-C)bis(dimethylglyoximato-N,N′)-(morpholine-N)cobalt(III)-monohydrate

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Summary

The title compound crystallizes in the monoclinic space group P21/n, with cell dimensions:a = 8.535(4) Å,b = 13.009(4) Å,c = 20.615(5) Å, β = 100.57(3)∘ and Z = 4. The central cobalt atom coordination is a slightly distorted octahedron, formed by five N-atoms (two glyoximes and morpholine) and one C-atom.

The interaction between the complex Co-units is weak: the strongest nearest neighbour interaction is formed by a hydrogen bridge in which the water molecule of crystallization acts as the donor part.

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Authors and Affiliations

  1. Department of Chemistry, University of Antwerp (U.I.A.), Universiteitsplein 1, B-2610, Wilrijk, Belgium

    Marc Van Hooste & Albert T. H. Lenstra

  2. Laboratory of Homogeneous Catalysis, Institute of Organic Chemistry, Polish Academy of Sciences, Kasprzaka 44, 00-961, Warszawa, Poland

    Michał Kwiecinski & Stanisław Tyrlik

Authors
  1. Marc Van Hooste
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  2. Albert T. H. Lenstra
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  3. Michał Kwiecinski
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  4. Stanisław Tyrlik
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Van Hooste, M., Lenstra, A.T.H., Kwiecinski, M. et al. Crystal structure oftrans-(benzyl-C)bis(dimethylglyoximato-N,N′)-(morpholine-N)cobalt(III)-monohydrate. Transition Met Chem 7, 50–53 (1982). https://doi.org/10.1007/BF00623809

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  • DOI: https://doi.org/10.1007/BF00623809

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