Summary
Several new polymeric complexes of general composition MOn(L)4X2 (where M = V, Zr and U; n = 1 or 2; X = Cl, Br, I, NO3 and NCS and L = N2H4, PhNHNH2 and Me2NNH2 have been synthesised and characterized by elemental and d.t. analyses and by magnetic measurements, electronic and i.r. spectra. The vanadyl(IV) complexes exhibit subnormal magnetic moments (1.26–1.36BM) possibly because of exchange interaction between vanadium(IV) ions. The thermal stability of hydrazine complexes fall in the order: Cl>Br>NCS>I. The M-N bond strength, as revealed, by v(M-N), decreases as: Me2NNH2>N2H4>PhNHNH2.
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References
J. R. Dilworth,Coord. Chem. Rev., 21, 129 (1976).
L. F. Audreith and B. A. Ogg,The Chemistry of Hydrazine, Wiley, New York, (1951).
M. Akbar Ali and S. E. Livingstone,Coord. Chem. Rev., 13, 101 (1974).
A. K. Srivastava and F. Tarli,J. Inorg. Nucl. Chem., 39, 1793 (1977).
A. K. Srivastava, P. C. Jain and A. L. Varshney,J. Inorg. Nucl. Chem., 42, 47 (1980).
A. K. Srivastava,Croatica Chim. Acta, 52, 293 (1979).
A. K. Srivastava,Transition Met. Chem., 5, 143 (1980).
V. V. Zelentsov,russ. J. Inorg. Chem., 7, 670 (1962).
A. P. Ginsberg, E. Koubek and H. J. Williams,Inorg. Chem., 5, 1956 (1966).
V. T. Kalinnikov, V. V. Zelentsov, O. N. Kuzmicheva and T. G. Aminov,russ. J. Inorg. Chem., 15, 341 (1970).
A. T. Casey and J. R. Thackray,Austr. J. Chem., 22, 2549 (1969).
C. C. Lee, A. Shyamal and L. J. Theriot,Inorg. Chem., 10, 1869 (1971).
S. N. Poddar, K. Dey, J. Haldar and H. S. Nathsankar,J. Indian Chem. Soc., 47, 743 (1970).
Y. Kuge and S. Yamada,Bull. Soc. Chem. Jpn., 43, 3972 (1970).
S. Yamada and Y. Kuge,Bull. Chem. Soc. Jpn., 42, 152 (1969).
L. Sacconi and U. Campigli,Inorg. Chem., 5, 606 (1966).
J. Selbin,Coord. Chem. Rev., 1, 293 (1966).
J. Selbin,Chem. Rev., 65, 153 (1965).
C. N. Sathyanarayana and C. C. Patel,Indian J. Chem., 3, 486 (1965).
L. G. Vanquickenborne and S. P. McGlynn,Theor. Chim. Acta, 9, 390 (1960).
S. K. Madan and H. H. Denk,J. Inorg. Nucl. Chem., 27, 1049 (1965).
P. A. Giguera and T. D. Liu,J. Chem. Phys., 20, 136 (1952).
D. Nicholls, M. Rowley and R. S. Swinetells,J. Chem. Soc., A, 980 (1966).
G. M. Barrow, R. H. Kneger and F. Basolo,J. Inorg. Nucl. Chem., 2, 340 (1956).
F. P. Bertin, I. Nakagawa, S. Muzushima, J. J. Lane and J. V. Quagliano,J. Am. Chem. Soc., 80, 525 (1958).
K. Nakamoto in A. E. Martell (Ed.),Infrared Spectra in A.C.S. (Monograph No. 168), 1971, p. 167.
S. K. Madan and A. M. Donohne,J. Inorg. Nucl. Chem., 28, 1330 (1966).
C. G. Barraclough, J. Lewis and R. S. Nyholm,J. Chem. Soc., 3552 (1959).
J. L. Burmeister,Coord. Chem. Rev., 1, 205 (1966);3, 225 (1968).
C. C. Addison, N. Logan, C. S. Wallwork and C. D. Garner,Quart Rev., 25, 289 (1971).
N. F. Curtis and Y. M. Curtis,Inorg. Chem., 4, 804 (1968).
A. B. P. Lever, E. Mantiovani and B. S. Ramaswamy,Can. J. Chem., 49, 1957 (1971).
V. T. Athavale and C. S. Padmanabhaiyer,J. Inorg. Nucl. Chem., 29, 1003 (1967).
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Presented in symposium on Frontiers of coordination chemistry, Allahabad University, Allahabad, Dec. 6–8, 1979.
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Srivastava, A.K., Agarwal, R.K., Srivastava, M. et al. Complexes of hydrazine and substituted hydrazines with some oxocations. Transition Met Chem 7, 41–44 (1982). https://doi.org/10.1007/BF00623807
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DOI: https://doi.org/10.1007/BF00623807