Summary
The ReOX2L(PPh3) complexes (X = Cl or Br and L =N-methylsalicylideneiminate,N-phenylsalicylideneiminate, halfN,N′-ethylenebis(salicylideneiminate) or 8-hydroxyquinolinate) react with dimethylphenylphosphine (PMe2Ph) to give ReOX2L(PMe2Ph) initially by displacement of the phosphine ligand and then the ReX2L(PMe2Ph)2 complexes with reduction of rhenium(V) to rhenium(III). The complexes were characterized by elemental analysis, magnetic susceptibility measurements and i.r. and1H n.m.r. spectra.
Similar content being viewed by others
References
U. Mazzi, E. Roncari, R. Rossi, V. Bertolasi, O. Traverso and L. Magon,Transition Met. Chem., 5, 289 (1980).
E. Roncari, U. Mazzi, R. Rossi, A. Duatti and L. Magon,Transition Met. Chem. 6, 169 (1981).
G. Bombieri, U. Mazzi, G. Gilli and F. Hernandez-Cano,J. Organometal. Chem., 159, 53 (1978).
D. D. Perrin, W. L. F. Armarego and D. R. Perrin,Purif. of Lab. Chemicals, Pergamon Press, 1966.
J. Chatt, G. J. Leigh, D. M. P. Mingos and R. J. Paske,J. Chem. Soc. A, 2636 (1968).
D. Shaw and E. W. Randall,J. Chem. Soc. Chem. Comm. 82 (1965).
E. W. Randall and D. Shaw,J. Chem. Soc. A, 2867 (1969).
J. M. Jenkins and B. L. Shaw,J. Chem. Soc. A, 770 (1966).
J. M. Jenkins, and B. L. Shaw,J. Chem. Soc. A, 1407 (1966).
J. M. Jenkins, M. S. Lupin and B. L. Shaw,J. Chem. Soc. A, 1787 (1966).
J. R. Moss and B. L. Shaw,J. Chem. Soc. A, 1793 (1966).
P. R. Brookes and B. L. Shaw,J. Chem. Soc. A, 1079 (1967).
B. L. Shaw and A. C. Smithies,J. Chem. Soc. A, 2784 (1968).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Duatti, A., Rossi, R., Marchi, A. et al. Reactivity of Schiff base rhenium(V) complexes with dimethylphenylphosphine. Transition Met Chem 6, 360–364 (1981). https://doi.org/10.1007/BF00623657
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/BF00623657