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Relationship between optical and structural properties of hydrogenated amorphous silicon

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Abstract

A series of experimental studies has been made on the relationship between optical and structural properties of hydrogenated amorphous silicon (a-Si:H) prepared under various conditions. It has been clarified by analysing the results that the shape of the energy spectrum near the band edge and the distribution of the valence-band tail states depend primarily on the structural disorder of the Si network in a-Si:H. On the other hand, the total content and the bonding mode of bonded hydrogen have little effects on these electronic properties of a-Si:H. It has also been found that the distribution of the valenceband tail states might be related to other unidentified factor(s) besides the structural disorder. The present results have been compared with those of the previous experimental and theoretical studies.

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References

  1. For example, seeSemiconductors and Semimetals, Vol. 21, Pt. B, ed. by J.I. Pankove (Academic, Orlando, FL 1984) Chaps. 2–4 and 6

    Google Scholar 

  2. P.D. Persans, A.F. Ruppert, S.S. Chan, G.D. Cody: Solid State Commun.51, 203 (1984)

    Google Scholar 

  3. E. Bustarret, E. Morgado: Solid State Commun.63, 581 (1987)

    Google Scholar 

  4. A.H. Mahan, P. Menna, R. Tsu: Appl. Phys. Lett.51, 1167 (1987)

    Google Scholar 

  5. N. Maley, J.S. Lannin: Phys. Rev. B36, 1146 (1987)

    Google Scholar 

  6. I. Sakata, S. Okazaki, M. Yamanaka, Y. Hayashi: Jpn. J. Appl. Phys.24, L428 (1985)

    Google Scholar 

  7. Y. Hayashi, M. Yamanaka, S. Okazaki: Unpublished data

  8. I. Sakata, Y. Hayashi, M. Yamanaka, H. Karasawa: J. Appl. Phys.52, 4334 (1981)

    Google Scholar 

  9. L. Ley: InThe Physics of Hydrogenated Amorphous Silicon II, ed. by J.D. Joannopoulos, G. Lucovsky, Topics Appl. Phys.56 (Springer, Berlin, Heidelberg 1984) pp. 61–168

    Google Scholar 

  10. G. Fortunato, F. Bruno, A. D'amico: J. Non-Cryst. Solids77 &78, 555 (1985)

    Google Scholar 

  11. M. Vaněček, J. Kočka, J. Stuchlik, Z. Kožišek, O. Stika, A. Třiska: Solar Energy Mater.8, 411 (1982)

    Google Scholar 

  12. J.S. Lannin, L.J. Pilione, S.T. Kshiragar, R. Messier, R.C. Ross: Phys. Rev. Lett.26, 3506 (1982)

    Google Scholar 

  13. T. Ishidate, K. Inoue, K. Tsuji, S. Minomura: Solid State Commun.42, 197 (1982)

    Google Scholar 

  14. I. Sakata, Y. Hayashi, M. Yamanaka, Y. Mori, M. Satoh, A. Ito, S. Okazaki: Bull. Electrotechnical Laboratory49, 160 (1985) (in Japanese)

    Google Scholar 

  15. C.J. Fang, K.J. Gruntz, L. Ley, M. Cardona, F.J. Demond, G. Müller, S. Kalbitzer: J. Non-Cryst. Solids35 &36, 255 (1980)

    Google Scholar 

  16. Y. Hishikawa, K. Watanabe, S. Tsuda, M. Ohnishi, Y. Kuwano: Jpn. J. Appl. Phys.24, 385 (1985)

    Google Scholar 

  17. S. Iizima, H. Okushi, A. Matsuda, S. Yamasaki, K. Nakagawa, M. Matsumura, K. Tanaka: In Proc. 11th Conf. on Solid State Devices (Publi. Office of Jpn. J. Appl. Phys., Tokyo 1980) pp. 521–526

  18. S. Yamasaki, N. Hata, T. Yoshida, H. Oheda, A. Matsuda, H. Okushi, K. Tanaka: J. Physique ColloqueC-4, Supplement au n∘ 10, C4–297 (1981)

    Google Scholar 

  19. R. Tsu: Solar Cells21, 19 (1987)

    Google Scholar 

  20. T. Watanabe, K. Zzuma, M. Nakatani, K. Suzuki, T. Sonobe, T. Shimada: Jpn. J. Appl. Phys.25, 1805 (1986)

    Google Scholar 

  21. A. Frova, A. Selloni: InTetrahedrally-Bonded Amorphous Semiconductors, ed. by D. Adler, H. Fritzsche (Plenum, New York 1985) pp. 271–285

    Google Scholar 

  22. K. Tanaka, S. Yamasaki: Solar Energy Mater.8, 277 (1982)

    Google Scholar 

  23. Z.E. Smith, S. Aljishi, S. Wagner: J. Non-Cryst. Solids97 &98, 775 (1987)

    Google Scholar 

  24. F. Yonezawa: InAmorphous Semiconductor Technologies and Devices, ed. by Y. Hamakawa (Ohmsha, Tokyo 1984) pp. 12–20

    Google Scholar 

  25. D.P. DiVincenzo, J. Bernholc, M.H. Brodsky: Phys. Rev. B28, 3246 (1983)

    Google Scholar 

  26. R.A. Street: InAmorphous Silicon SemiconductorsPure and Hydrogenated, ed. by A. Madan, M. Thompson, D. Adler, Y. Hamakawa (Materials Research Society, Pittsburgh 1987) Vol. 95, pp. 13–22

    Google Scholar 

  27. D.E. Carlson: InDisordered Semiconductors, ed. by M.A. Kastner, G.A. Thomas, S.R. Ovshinsky (Plenum, New York 1987) pp. 613–620

    Google Scholar 

  28. H. Okushi, S. Yamasaki, A. Matsuda, K. Tanaka: J. NonCryst. Solids77 &78, 1015 (1985)

    Google Scholar 

  29. X. Xu, A. Morimoto, M. Kumeda, T. Shimizu: Jpn. J. Appl. Phys.26, L1818 (1987)

    Google Scholar 

  30. Z.E. Smith, S. Wagner: Phys. Rev. Lett.59, 688 (1987)

    Google Scholar 

  31. W.B. Jackson, S.M. Kelso, C.C. Tsai, J.W. Allen, S.-J. Oh: Phys. Rev. B31, 5187 (1985)

    Google Scholar 

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Sakata, I., Yamanaka, M., Okazaki, S. et al. Relationship between optical and structural properties of hydrogenated amorphous silicon. Appl. Phys. A 48, 295–304 (1989). https://doi.org/10.1007/BF00618889

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