Summary
Rate constants are reported and discussed for several substitutions of inorganic complexes in ethylene carbonate (1,3-dioxolan-2-one) + water and in propylene carbonate (4-methyl-1,3-dioxolan-2-one) + water solvent mixtures. The reactions include aquation ofcis- and oftrans-[Co(en)2Cl2]+, aquation oftrans-[Cr(OH2)4Cl2]+, bromide substitution at [Pd(Et4dien)Cl]+, thiourea substitution atcis-[Pt(4-NCpy)2Cl2], and aquation and cyanide attack at [Fe(X-phen)3]2+ cations.
Similar content being viewed by others
References
J. Burgess,Inorg. React. Mechanisms, 1, 202 (1971);3, 312 (1974);4, 236 (1976);5, 260 (1977); and refs. therein.
W. H. Lee, in J. J. Lagowski (Ed.),The Chemistry of Non-Aqueous Solvents, Academic Press, New York, 1976, vol. 4, ch. 6.
N. F. Catherall and A. G. Williamson,J. Ckem. Eng. Data, 16, 335 (1971).
L. A. Pohoryles and S. Sarel,Comptes Rendus, 245, 2321 (1957).
I. Levin, L. A. Pohoryles, S. Sarel and V. Usieli,J. Chem. Soc., 3949 (1963).
M. L'Her, D. Morin-Bozec and J. Courtot-Coupez,J. Electroanal. Chem., 55, 133 (1974).
J.-Y. Cabon, M. L'Her and J. Courtot-Coupez,ibid., 64, 219 (1975).
B. G. Cox,Ann. Rep. Chem. Soc., 70A, 249 (1973).
I. A. Vasil'ev and A. D. Korkhev,Russ. J. Phys. Chem., 47, 1527 (1973); P. T. Thompson, R. E. Taylor and R. H. Wood,J. Chem. Thermodynamics, 7, 547 (1975); S. Y. Lam and R. L. Benoit,Can. J. Chem., 52, 718 (1974).
M. J. Blandamer and J. Burgess,Chem. Soc. Revs., 4, 55 (1975).
J. Burgess,J. Chem. Soc. A, 2351 (1970).
H. Holand,J. Solution Chem., 5, 773 (1970).
H. L. Friedman and C. V. Krishnan in F. Frank (Ed.),Water — A Comprehensive Treatise, Plenum Press, New York, 1973, vol. 3, ch. 1.
J. Burgess,J. Chem. Soc. A, 2703 (1970); J. Burgess and M. G. Price,ibid., 3108 (1971).
M. J. Blandamer, J. Burgess, M. Dupree and S. J. Hamshere,J. Chem. Research, (S) 58, (M) 0728 (1978).
e.g. J. Burgess,Inorg. React. Mechanisms, 3, 163 (1974); and refs. therein.
J. Burgess,J. Chem. Soc. Dalton Trans., 825 (1973).
F. Basolo,Advances in Chem., 49, 81 (1965).
D. A. Palmer and H. Kelm,Inorg. Chim. Acta, 14, L27 (1975).
Y.-C. Wu and H. L. Friedman,J. Phys. Chem., 70, 2020 (1966); C. V. Krishnan and H. L. Friedman,ibid., 74, 3900 (1970).
M. J. Blandamer, J. Burgess and S. J. Hamshere, unpublished observations.
O. D. Bonner, C. F. Jordan, R. K. Arisman and J. M. Bednarek,J. Chem. Thermodynamics, 8, 1173 (1976).
J. Burgess,J. Chem. Soc. A, 1085 (1968).
J. Burgess,J. Chem. Soc. A, 1899 (1969).
M. J. Blandamer, J. Burgess and J. G. Chambers,J. Chem. Soc. Dalton Trans., 606 (1976); M. J. Blandamer, J. Burgess, J. G. Chambers, R. I. Haines and H. E. Marshall,ibid., 165 (1977).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Blandamer, M.J., Burgess, J., Hamshere, S.J. et al. Kinetics of substitution reactions of transition metal complexes in 1,3-dioxolan-2-one + water and 4-methyl-1,3-dioxolan-2-one + water solvent mixtures. Transition Met Chem 4, 77–81 (1979). https://doi.org/10.1007/BF00618829
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00618829