Skip to main content
SpringerLink
Log in

Crystal structure of tris(2-pyridylthio-2-pyridinium)pentaisothiocyanato-dioxouranate(VI)

  • Full Papers
  • Published:
Transition Metal Chemistry Aims and scope Submit manuscript

Summary

The crystal structure of [DPSH] +3 [UO2[NCS)5]3− (DPSH = 2 pyridylthio-2-pyridinium) has been determined by standard methods using diffractometer data. Crystals are monoclinic, space groupP21/a, witha=33.16 (3),b=16.68(2),c=7.85(1) Å, andβ=97.3(1)∘; Dc=1.65 g · cm−3 for Z=4. The structure has been refined to R=5.8% by least squares methods. Five thiocyanate groups are equatorially bonded to the linear uranyl group. The mean of the five U-N, N-C, and C-S bond distances are 2.45, 1.17, and 1.59 Å respectively. The protonated DPS molecules have the N,N-inside conformations.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. G. C. Pappalardo and A. Seminara,J. Inorg. Nucl. Chem., 38, 1993 (1976).

    Google Scholar 

  2. A. Forchioni, V. Librando and G. C. Pappalardo,J. Chem. Soc. Dalton Trans., 638, (1977).

  3. S. Ahrland.Acta Chem. Scand., 3, 374 (1949).

    Google Scholar 

  4. C. F. Baes Jr. and N. J. Meyer,Inorg. Chem., 1, 780 (1962).

    Google Scholar 

  5. A. C. T. North, D. C. Phillips and F. S. Mathews,Acta Crystallogr., A24, 351 (1968).

    Google Scholar 

  6. D. T. Cromer and J. T. Waber,Acta Crystallogr., 18, 104 (1965).

    Google Scholar 

  7. D. T. Cromer,Acta Crystallogr., 18, 17 (1965).

    Google Scholar 

  8. X-ray System — Version of June 1972, Technical Report TR-192, University of Maryland, U.S.A.

  9. G. Sheldrick, SHELX-76, Program for Crystal Structure Determination, University of Cambridge (1976).

  10. E. G. Arutyunyan and M. A. Porai-Koshits,Zhur. Struky. Khim., 4, 110 (1963).

    Google Scholar 

  11. C. Bombieri, P. T. Moseley and D. Brown,J. Chem. Soc. Dalton Trans., 1520 (1975).

  12. C. Chachaty, G. C. Pappalardo and G. Scarlata,J. Chem. Soc. Perkin Trans. II, 1234 (1976).

    Google Scholar 

  13. G. Bombieri, E. Forsellini and R. Graziani,Acta Crystallogr., B 34, 2622 (1978).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Laboratorio di Chimica e Tecnologia dei Radioelementi del C.N.R., Padova, Italy

    Gabriella Bombieri & Eleonora Forsellini

  2. Istituto di Chimica Generale, Università di Padova, Italy

    Rodolfo Graziani

  3. Istituto di Chimica Generale, Università di Catania, Italy

    Guiseppe C. Pappalardo

Authors
  1. Gabriella Bombieri
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Eleonora Forsellini
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Rodolfo Graziani
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Guiseppe C. Pappalardo
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Bombieri, G., Forsellini, E., Graziani, R. et al. Crystal structure of tris(2-pyridylthio-2-pyridinium)pentaisothiocyanato-dioxouranate(VI). Transition Met Chem 4, 70–72 (1979). https://doi.org/10.1007/BF00618827

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00618827

Keywords

Search

Navigation