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Dioxouranium(VI) complexes with potentially dibasic tridentate schiff base ligands. Characterization of the uranyl complexes of salicylaldehyde-2-hydroxyanil and its substituted derivatives

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Summary

Some 1∶1, 2∶3, and 1∶2 uranyl complexes of salicylaldehyde-2-hydroxyanil (H2SAP) and its substituted (3-methoxy-, 5-nitro-, 5-chloro- and 3,5-dichloro-) derivatives have been synthesized and characterized. The conductivity, i.r.,1H n.m.r. and visible spectroscopic data allow discussion of the varying ligating behaviour of the potentially dibasic tridentate Schiff base ligands toward dioxouranium(VI).

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Authors and Affiliations

  1. Guelph-Waterloo Centre for Graduate Work in Chemistry, Guelph Campus, Department of Chemistry, University of Guelph, N1G 2W1, Guelph, Ontario, Canada

    Elmer C. Alyea, Abdul Malek & Azizul I. Kazi

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  1. Elmer C. Alyea
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  2. Abdul Malek
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  3. Azizul I. Kazi
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Alyea, E.C., Malek, A. & Kazi, A.I. Dioxouranium(VI) complexes with potentially dibasic tridentate schiff base ligands. Characterization of the uranyl complexes of salicylaldehyde-2-hydroxyanil and its substituted derivatives. Transition Met Chem 6, 223–226 (1981). https://doi.org/10.1007/BF00618229

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