Transition Metal Chemistry

, Volume 6, Issue 4, pp 223–226 | Cite as

Dioxouranium(VI) complexes with potentially dibasic tridentate schiff base ligands. Characterization of the uranyl complexes of salicylaldehyde-2-hydroxyanil and its substituted derivatives

  • Elmer C. Alyea
  • Abdul Malek
  • Azizul I. Kazi
Full Papers

Summary

Some 1∶1, 2∶3, and 1∶2 uranyl complexes of salicylaldehyde-2-hydroxyanil (H2SAP) and its substituted (3-methoxy-, 5-nitro-, 5-chloro- and 3,5-dichloro-) derivatives have been synthesized and characterized. The conductivity, i.r.,1H n.m.r. and visible spectroscopic data allow discussion of the varying ligating behaviour of the potentially dibasic tridentate Schiff base ligands toward dioxouranium(VI).

Keywords

Physical Chemistry Inorganic Chemistry Uranyl Schiff Base Schiff 

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Copyright information

© Verlag Chemie GmbH 1981

Authors and Affiliations

  • Elmer C. Alyea
    • 1
  • Abdul Malek
    • 1
  • Azizul I. Kazi
    • 1
  1. 1.Guelph-Waterloo Centre for Graduate Work in Chemistry, Guelph Campus, Department of ChemistryUniversity of GuelphGuelphCanada

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