Abstract
It is shown that it is basically possible to model plasma-chemical methane conversion using a kinetic concept regardless of the kind of plasma, i.e., the kind of activation. While the temporal plasma-chemical decomposition of methane is controlled by a first-order rate equation, the temporal product formation can be described by a set of first-order consecutive reactions. Prolonged portions of constant product concentrations in the temporal product formation curves were explained by the assumption of an equilibrium between forward and reverse reactions. The modeling revealed the special role of the re-formation of dissociated molecules.
Similar content being viewed by others
References
R. Mach and H. Drost, Proc. of ISPC-6, Vol. 2, M. J. Boulos and R. J. Munz, eds (Sherbroke University Press, Montreal, 1983).
H.-D. Klotz, H. Drost, and H.-J. Spangenberg,Z. Phys. Chem. 261, 201–210 (1980).
J. Rutkowsky, H. Drost, and R. Mach,Beitr. Plasmaphys. 23, 181–191 (1983).
W. A. Alekperow, M. B. Grintshak, Z. Kecej, A. A. Owsjanikow, and L. S. Polak, inPlasma-chemical Processes, L. S. Polak, ed. (Nauka, Moscow, 1979), pp. 105–136.
P. F. Baddour and R. S. Timmins,The Application of Plasmas to Chemical Processing, Pergamon Press, New York (1967).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Drost, H., Rutkowsky, J., Mach, R. et al. Plasma-chemical methane conversion under nonthermal and thermal conditions: An attempt toward uniform kinetic modeling. Plasma Chem Plasma Process 5, 283–291 (1985). https://doi.org/10.1007/BF00615127
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/BF00615127