Skip to main content
Log in

Luminescent properties of some ternary complexes of europium with thenoyltrifluoroacetone and organic bases

  • Published:
Journal of Applied Spectroscopy Aims and scope

Abstract

The relative intensity of the fluorescence I and the mean lifetimeτ of the excited state of the europium ion in ternary thenoyltrifluoroacetonate complexes with organic nitrogen-containing bases have been studied. The introduction of a molecule of the base into the complex alters the structure of the spectrum slightly. The mean lifetime of the excited state of the Eu ion is shorter in solutions of the complexes in all organic solvents than in the solid form. There is an approximate correlation between I and τ for the europium ion in organic solvents.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. V. V. Kuznetsova and A. N. Sevchenko, Izv. AN SSSR, ser. fiz.23, 3, 1959.

    Google Scholar 

  2. G. A. Crosby, R. E. Whan, and R. M. Alire, J. Chem. Phys.,34, 743, 1961.

    Google Scholar 

  3. V. V. Kuznetsova and A. N. Sevchenko, Fizich. problemy spektroskopii,1, 236, 1962.

    Google Scholar 

  4. M. L. Bhaumik and L. R. Tannenbaum, J. Phys. Chem.,67, 2500, 1963.

    Google Scholar 

  5. M. L. Bhaumik, H. Lyons, and P. C. Fletcher, J. Chem. Phys.,38, 568, 1963.

    Google Scholar 

  6. H. Samelson, A. Lempicki, V. A. Brophy, and C. Brecher, J. Chem. Phys.,40, 2547, 1964.

    Google Scholar 

  7. F. Halverson, J. S. Briner, and J. R. Leto, J. Chem. Phys.,40, 2790, 1964.

    Google Scholar 

  8. S. G. Rautian and I. I. Sobel'man, Opt. i spektr.,10, 135, 1961.

    Google Scholar 

  9. P. A. Batulin, L. D. Derkacheva, et al., Opt. i spektr.,18, 526, 1965.

    Google Scholar 

  10. A, Lempicki, H. Samelson, and C. Brecher, J. Chem. Phys.,41, 1214, 1964.

    Google Scholar 

  11. A. N. Sevchenko and V. V. Kuznetsova, in collection: The Rare Earth Elements [in Russian], Izd. Nauka, Moscow, 358. 1963.

    Google Scholar 

  12. L. I. Kononenko, N. S. Poluektov, and M. P. Nikonova, Zav. lab.,30, 779, 1964.

    Google Scholar 

  13. S. M. Lee and L. J. Nugent, J. Inorg. Nucl. Chem.,26, 2306, 1964.

    Google Scholar 

  14. R. G. Charles and R. C. Ohlman, J. Inorg. Nucl. Chem.,27, 119, 1965.

    Google Scholar 

  15. M, Kleinerman, R. J. Hovey, and D. O. Hoffman, J. Chem. Phys.,41, 4009, 1964.

    Google Scholar 

  16. N. S. Poluektov, L. I. Kononenko, R. A. Vitkun, and M. P. Nikonova, Opt. i. spektr.,17, 73, 1965.

    Google Scholar 

Download references

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Melent'eva, E.V., Kononenko, L.I., Koltunova, E.G. et al. Luminescent properties of some ternary complexes of europium with thenoyltrifluoroacetone and organic bases. J Appl Spectrosc 5, 245–249 (1966). https://doi.org/10.1007/BF00605836

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00605836

Keywords

Navigation