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Luminescent Properties of Europium(III) Complexes with Quinaldic Acid and Sulfur–Containing Neutral Ligands

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Abstract

The luminescent heteroligand complexes of europium(III) with quinaldic acid and sulfur-containing neutral ligands Eu(Quin)3∙D∙3H2O (Quin–quinaldic acid, D–dimethyl sulfoxide or dihexyl sulfoxide) and Eu(Quin)3∙3H2O have been obtained. Their composition and structure have been determined. The thermal and spectral-luminescent properties of the heteroligand europium(III) complexes have been studied. The quinaldate ion has been found to coordinate to the europium(III) ion as a bidentate ligand. The Stark structure of 5D0–7Fj (j = 0, 1, 2) transitions in the low-temperature luminescence spectra of the europium(III) complexes has been analyzed

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Funding

This study was financially supported by the Ministry of Education and Science in the scope of the State Task (no. 0265-2014-0001).

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Authors and Affiliations

  1. Institute of Chemistry, Far Eastern Branch of the Russian Academy of Sciences, Vladivostok, 690022, Russia

    I. V. Kalinovskaya

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  1. I. V. Kalinovskaya
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Correspondence to I. V. Kalinovskaya.

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Russian Text © The Author(s), 2019, published in Zhurnal Obshchei Khimii, 2019, Vol. 89, No. 12, pp. 1909–1914.

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Kalinovskaya, I.V. Luminescent Properties of Europium(III) Complexes with Quinaldic Acid and Sulfur–Containing Neutral Ligands. Russ J Gen Chem 89, 2420–2423 (2019). https://doi.org/10.1134/S1070363219120156

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  • DOI: https://doi.org/10.1134/S1070363219120156

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