Journal of Applied Spectroscopy

, Volume 5, Issue 1, pp 8–10 | Cite as

Use of two parallel thermochemical reactions to increase the sensitivity of the spectrographic determination of zirconium in molybdenum

  • A. A. Frishberg
Article

Abstract

The use of two parallel thermochemical reactions, sulfidization and fluorination, to increase the sensitivity of the spectrographic determination of zirconium in molybdenum was investigated. To determine zirconium quantitatively in amounts of 1x10−4 or more the molybdenum is first converted to the trioxide, and the thermochemical reactions are then used to form volatile zirconium tetrafluoride which evaporates in the arc, leaving the nonvolatile molybdenum sulfide behind.

Keywords

Analytical Chemistry Sulfide Zirconium Molybdenum Molecular Structure 

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References

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    B.V. Nekrasov, Course in General Chemistry [in Russian], Goskhimizdat, Moscow, 529, 1952.Google Scholar
  2. 2.
    A.N. Krestovnikov, L.P. Vladimirov, B.S. Gulyanitskii, and A. Ya. Fisher, Reference Book of Equilibrium Calculations for Metallurgical Reactions [in Russian], GNTI, Moscow, 51, 1963.Google Scholar

Copyright information

© The Faraday Press, Inc. 1969

Authors and Affiliations

  • A. A. Frishberg

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