Abstract
Radical copolymerization of methyl methacrylate (MMA, M1) and N-(4-bromophenyl) maleimide (N4BrPhMI, M2) in dioxane at 60 °C was performed with AIBN as initiator. Analysis of composition data points was carried out to a terminal model copolymerization. Using 1H, 13C and DEPT NMR measurements, the observed resonances were assigned. Glass transition temperatures were determined by DSC and a linear correlation was found between the Tg values and M2 content of the copolymers.
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T. Otsu, A. Tatsumi and A. Matsumoto,J. Polym. Sci., Polym. Lett., 24, 113 (1986).
J. M. Barrales-Rienda, J. I. Gozalez de la Campa and J. Gonzalez Ramos,J. Macromol. Sci.-Chem., A11, 267 (1977).
A. A. Mohamed, F. H. Jebrael and M. Z. Elsabee,Macromolecules, 19, 32 (1986).
T. Oishi, M. Moriwaki, M. Momoi and M. Fujimoto,J. Macromol. Sci.-Chem., A26, 961 (1989).
A. Ryttel and M. Kucharski,Acta Polymerica, 40, 62 (1989).
D. D. Fles, R. Vukovic F. and Ranogajec,J. Polym. Sci., Polym. Chem., 27, 3327 (1989).
G. Schmidt-Naake, H. Schmidt, B. Litauszki and H. Schmutzler,Wiss. Z. Techn. Univers. Dresden, 38, 131 (1989).
D. J. T. Hill, J. H. O'Donnell and P. W. O'Sullivan,Macromolecules, 15, 960 (1982).
K. G. Olson and G. B. Butler,Macromolecules, 16, 707 (1983).
K. G. Olson and G. B. Butler,Macromolecules, 17, 2480 and 2486 (1984).
G. S. Prementine, S. A. Jones and D. A. Tirrell,Macromolecules, 22, 770 (1989).
Z. Florjanczyk and W. Krawiec,Makromol. Chem., 190, 2141 (1989).
T. Hagiwara, T. Shimizu, T. Someno, T. Yamagishi, H. Hamana and T. Narita,Macromolecules, 21, 3324 (1989).
T. Hagiwara, T. Shimizu, T. Uda, H. Hamana and T. Narita,J. Polym. Sci., Polym. Chem., 28, 1225 (1990).
C. I. Simionescu and M. Grigoras,J. Polym. Sci., Polym. Lett., 28, 39 (1990).
T. Kelen F. Tüdős, T. Földes-Bereznikh and B. Turcsányi,J. Macromol. Sci.-Chem., A10, 1513 (1975).
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Borbély, J., Kelen, T., Konsulov, V.B. et al. Synthesis and characterization of poly-(methyl methacrylate-co-N-4-bromophenyl maleimide). Polymer Bulletin 26, 253–258 (1991). https://doi.org/10.1007/BF00587966
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DOI: https://doi.org/10.1007/BF00587966