Skip to main content
SpringerLink
Log in

Mössbauer study of YBa2(Cu1−x Fex)3Oy from an aspect of distribution of Fe

  • Section III.5: High Tc Superconductivity
  • Published:
Hyperfine Interactions Aims and scope Submit manuscript

Abstract

Fe Mössbauer spectra have been measured systematically in YBa2(Cu1−x Fex)3Oy prepared by two different heat treatments: the usual treatment (O) and the heat treatment including that under lower oxygen fugacity at high temperatures followed by the oxidation process at low temperatures (NO). From the analysis of the results in terms of binomial random probability, it has been found that the Fe distribution in the Cu(1) site is almost random in the heat treatment (O). Here, the D1 and D2 components in the Mössbauer spectra, which have been assigned to the 4 and 6 oxygen coordinated Fe ions in the Cu(1) site respectively, should correspond to the monomer and cluster Fe ions. In the heat treatment (NO), some of the Fe ions are transferred to the Cu(2) site and there exist only cluster Fe ions in the Cu(1) site, resulting in the characteristic change of macroscopic properties of this system.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Y. Maeno et al., Nature 328 (1987) 512.

    Google Scholar 

  2. J.M. Tarascon et al., Phys. Rev. B 37 (1988) 7458.

    Google Scholar 

  3. J.L. Hodeau et al., Physica C 153–155 (1988) 582.

    Google Scholar 

  4. Y. Xu et al., Phys. Rev. B 39 (1989) 6667.

    Google Scholar 

  5. B.D. Dunlap et al., Physica C 158 (1989) 397.

    Google Scholar 

  6. F. Bridges et al., Phys. Rev. B 39 (1989) 11603.

    Google Scholar 

  7. S. Katsuyama et al., Mater. Res. Bull. 24 (1989) 603.

    Google Scholar 

  8. S. Katsuyama et al., Physica C 165 (1990) 404.

    Google Scholar 

  9. T. Shibata et al., Japan. J. Appl. Phys. 30 (1991) L175.

  10. H. Mazaki et al., Japan. J. Appl. Phys. 28 (1989) L1909.

  11. S. Nasu et al.,Proc. JIMIS-5, Trans. JIM 29 (1988) Suppl. p. 543.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Kyoto University, 606-01, Kyoto, Japan

    K. Yoshimura, T. Shibata, S. Katsuyama, H. Nagai & K. Kosuge

  2. Department of Materials Science and Engineering, Osaka University, 565, Suita, Japan

    S. Katsuyama & H. Nagai

Authors
  1. K. Yoshimura
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. T. Shibata
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. S. Katsuyama
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. H. Nagai
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. K. Kosuge
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Yoshimura, K., Shibata, T., Katsuyama, S. et al. Mössbauer study of YBa2(Cu1−x Fex)3Oy from an aspect of distribution of Fe. Hyperfine Interact 79, 863–866 (1993). https://doi.org/10.1007/BF00567618

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00567618

Keywords

Search

Navigation