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The titaniummolten glass system: interactions and wetting

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Abstract

Titanium interactions with three molten glasses based on sodium disilicate, with additions of TiO2 or La2O3, are studied under very reducing conditions, and the kinetics of spreading and equilibrium contact angles are determined. Titanium enters the molten glass as Ti3+, as shown by EPR spectrometry. Redox reactions occurring at solid—liquid interface and inside bulk glass are studied, and their influence on drop equilibrium is analysed.

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References

  1. R. M. King,The Glass Industry 23 (1942) 421.

    Google Scholar 

  2. G. J. Copley, A. D. Rivers andR. Smith,J. Mater. Sci. 10 (1975) 1285.

    Google Scholar 

  3. G. J. Copley andA. D. Rivers,ibid,10 (1975) 1291.

    Google Scholar 

  4. J. P. Leduc,Verres Refract. 29 (1975) 83, 133.

    Google Scholar 

  5. G. A. Holmquist,Berkeley-Lawrence Berk. Lab., M.Sc. Thesis, 1975.

  6. M. P. Borom, J. A. Longwell andJ. A. Pask,J. Amer. Ceram. Soc. 50 (1967) 61.

    Google Scholar 

  7. M. P. Borom andJ. A. Pask,ibid,51 (1968) 490.

    Google Scholar 

  8. C. E. Hoge, J. J. Brennan andJ. A. Pask,ibid,56 (1973) 51.

    Google Scholar 

  9. R. M. Fulrath, S. P. Mitoff andJ. A. Pask,ibid,40 (1957) 269.

    Google Scholar 

  10. M. L. Volpe, R. M. Fulrath andJ. A. Pask,ibid,42 (1959) 102.

    Google Scholar 

  11. R. W. Cline, R. M. Fulrath andJ. A. Pask,ibid,44 (1961) 423.

    Google Scholar 

  12. K. K. Visotskis,Zh. Prikl. Khim. 39 (1966) 1645.

    Google Scholar 

  13. I. J. McColm andC. Dimbylow,J. Mater. Sci. 9 (1974) 1320.

    Google Scholar 

  14. R. E. Johnson Jr.,J. Phys. Chem. 63 (1959) 1955.

    Google Scholar 

  15. W. A. Weyl andE. C. Marboe, “Constitution of Glasses”, Vol. 2 (John Wiley, New York, 1964) Chapter XXIII.

    Google Scholar 

  16. M. P. Borom andJ. A. Pask,J. Amer. Ceram. Soc. 49 (1966) 1.

    Google Scholar 

  17. W. A. Weyl andE. C. Marboe, “Constitution of Glasses”, Vol. 2. (John Wiley, New York, 1964) p. 757.

    Google Scholar 

  18. M. H. Manghnani,J. Amer. Ceram. Soc. (1972) 360.

  19. D. K. Dubrova andA. D. Shnypikov,Inorg. Mater. 2 (1966) 1417.

    Google Scholar 

  20. A. Passerone, E. Biagini andV. Lorenzelli,Ceramurgia 5 (1975) 81.

    Google Scholar 

  21. N. R. Yafaev andYu. V. Yablokov,Soviet Phys.-Solid State 4 (1962) 1123.

    Google Scholar 

  22. S. Arafa andA. Bishay,Phys. Chem. Glasses 11 (1970) 76.

    Google Scholar 

  23. K. Denbigh, “The Principles of Chemical Equilibrium” (Cambridge University Press, Cambridge, 1955) p. 167.

    Google Scholar 

  24. O. Kubaschewsky andE. L. L. Evans, “Metallurgical Thermochemistry”, (Pergamon Press, London, 1956).

    Google Scholar 

  25. W. D. Johnston,J. Amer. Ceram. Soc. 47 (1964) 198.

    Google Scholar 

  26. W. D. Johnston,ibid,48 (1965) 184.

    Google Scholar 

  27. S. B. Holmquist,ibid,49 (1966) 228.

    Google Scholar 

  28. W. D. Johnston andA. Chelko,ibid,49 (1966) 562.

    Google Scholar 

  29. A. Passerone, V. Lorenzelli andE. Biagini,Ann. Chim. Rome 52 (1972) 276.

    Google Scholar 

  30. D. Simon, C. Perrin andJ. Bardelle, Coll. Europ. Metall. sous vide, Lilla, France 7–9 Oct. 1975.

    Google Scholar 

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Authors and Affiliations

  1. Centro Studi di Chimica e Chimica Fisica Applicata alle Caratteristiche di Impiego del Materiali del C.N.R., Fiera del Mare, P. le Kennedy, Pad. D, Genova, Italy

    A. Passe Rone, G. Valbusa & E. Biagini

Authors
  1. A. Passe Rone
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  2. G. Valbusa
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  3. E. Biagini
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Passe Rone, A., Valbusa, G. & Biagini, E. The titaniummolten glass system: interactions and wetting. J Mater Sci 12, 2465–2474 (1977). https://doi.org/10.1007/BF00553934

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  • DOI: https://doi.org/10.1007/BF00553934

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