Abstract
A simple thermodynamic model of the solid-liquid interface in binary systems is presented and used as a means of estimating the solid-liquid interfacial energy, γSL, in such systems. The model is extended to pseudo-binary systems such as transition metal carbide/liquid metal systems. In combination with wetting data the estimated γSL values can be used to estimate the surface energy of the solid, γSV. In most cases, estimated values of γSL and γSV are in good agreement with experimentally determined values.
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N. Eustathopoulos, J. C. Joud and P. Desre, J. Chim. Phys. 11, 12 (1972) 1599.
Idem, ibid. 71 (1974) 777.
L. Coudurier, N. Eustathopoulos, P. Desre and A. Passerone, Acta Met. 26 (1978) 465.
A. R. Miedema and F. J. A. Broeder, Z. Metallkunde 70 (1979) 14.
E. D. Hondros, “Physicochemical Measurements in Metals Research” Vol. IV edited by R. A. Rapp (Interscience, New York, 1970) p. 293.
L. Kaufmann and H. Bernstein, “Computer Calculation of Phase Diagrams” (Academic Press, New York and London, 1970).
W. A. Miller and G. A. Chadwick, Acta Met. 15 (1967) 607.
W. R. Tyson and W. A. Miller, Surface Science 62 (1977) 267.
H. G. Frey and H. Holleck, KFK-Ext 6/74-5 Report of the Atomic Energy Centre, Karlsruhe (1974) p. 1.
S. Nazaré and G. Ondracek, KFK-Ext 6/74-5 Report of the Atomic Energy Centre, Karlsruhe (1974) p. 14.
G. Grimvall and S. SjÖdin, Physica Scripta 10 (1974) 340.
N. Eustathopoulos, L. Coudurier, J. C. Joud and P. Desre, J. Crystal Growth 33 (1976) 105.
Idem, J. Chim. Phys. 71 (1974) 1465.
Y. N. Levin and G. I. Ivantsov, Fiz. Met. Metalloved 16 (1963) 535.
E. N. Hodkin, M. G. Nicholas and D. M. Poole, J. Less Common Metals 20 (1970) 93.
D. A. Mortimer and M. G. Nicholas, J. Mater. Sci. 5 (1970) 149.
M. Humenik and W. D. Kingery, J. Amer. Ceram. Soc. 37 (1954) 18.
R. Warren, Metallography 9 (1976) 183.
R. Warren and M. B. Waldron, Nature Phys. Sci. 235 (1972) 73.
E. N. Hodkin, D. A. Mortimer, M. G. Nicholas and D. M. Poole, J. Nucl. Mater. 39 (1971) 59.
W. C. Ballamy and E. Hucke, TMS-AIME Paper No. A70-2 (1970).
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Warren, R. Solid-liquid interfacial energies in binary and pseudo-binary systems. J Mater Sci 15, 2489–2496 (1980). https://doi.org/10.1007/BF00550752
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DOI: https://doi.org/10.1007/BF00550752