Conclusions
A considerable effect of structural-physical properties and molecular dynamics of the polymer as a solid on the process of radical graft polymerization to fibres from thermoplastic polymers which have been spun from the melt has been found.
In the case of heterophase graft polymerization of vinyl monomers to polypropylene fibre, it has been shown that orderedness of the polymer structure primarily affects the initiation stage.
High kinetic parameters of heterophase graft polymerization in oriented systems from thermoplastic polymers can be realized only at temperatures which exceed the glass point of the polymer matrix.
Similar content being viewed by others
Literature cited
Z. A. Rogovin and L. S. Gal'braikh, Chemical Transformations and Modification of Cellulose [in Russian], Khimiya, Moscow (1979).
B. P. Morin, Doctoral Dissertation, VNIIVproekt, Moscow (1978).
S. É. Shalabi, I. S. Afanas'eva, et al., Khim. Volokna, No. 3, 32–33 (1984).
T. V. Druzhinina, Yu. D. Andrichenko, G. A. Gabrielyan, and Z. A. Rogovin, Second International Symposium on Man-made Fibres, Kalinin, (1981). Preprints, Vol. 5, pp. 223–229.
Yu. D. Andrichenko, T. V. Druzhinina, et al., Tekst. Prom-st', No. 3, 54 (1982).
Yu. A. Yablochkina et al., Khim. Volokna, No. 2, 45–47 (1980).
Yu. S. Andrichenko, T. V. Druzhinina, et al., Khim. Volokna, No. 4, 40–41 (1982).
Yu. D. Andrichenko, T. V. Druzhinina, et al., Tekst. Prom-st', No. 12, 39–40 (1982).
T. A. Litvinova et al., Khim. Volokna, No. 1, 20–21 (1984).
L. G. Privalova et al., Vysokomol. Soed., Ser. A, No. 8, 1891–1899 (1980).
N. M. Émanuél' and A. L. Buchachenko, The Chemical Physics of Aging and Stabilization of Polymers [in Russian], Khimiya, Moscow (1982).
N. Yu. Pimonenko, G. A. Gabrielyan, et al., Vysokomol. Soed., Ser. A, No. 3, 518–523 (1985).
Additional information
Moscow Textile Institute. Translated from Khimicheskie Volokna, No. 1, pp. 7–9, January–February, 1987.
Rights and permissions
About this article
Cite this article
Druzhinina, T.V. Some features of heterophase graft polymerization on synthetic fibers from thermoplastic polymers. Fibre Chem 19, 1–4 (1987). https://doi.org/10.1007/BF00544605
Issue Date:
DOI: https://doi.org/10.1007/BF00544605