Journal of Materials Science

, Volume 27, Issue 16, pp 4531–4535 | Cite as

Effects of amines on the formation of β-ferric oxide hydroxide

  • T. Ishikawa
  • T. Takeda
  • K. Kandori
Papers

Abstract

Colloidal particles of β-ferric oxide hydroxide (β-FeOOH) were prepared by ageing an FeCl3 solution at 100°C in the presence of various amines with different numbers of nitrogen atoms. The particle and crystallite sizes of the formed β-FeOOH decreased with increasing concentration of amines, but the particles produced contained no amine. The influence of triethanolamine on the growth of β-FeOOH particles was more marked than those of ethylenediamine, diethylenetriamine and triaminotriethylamine. The adsorption isotherms of nitrogen and water on the formed particles of different size were measured and surface fractal analysis was performed.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    W. O. Milligan and H. B. Weiser, J. Phys. Chem. 39 (1935) 25.Google Scholar
  2. 2.
    L. M. Kolthoff and J. Moskovitz, J. Amer. Chem. Soc. 58 (1936) 777.Google Scholar
  3. 3.
    L. J. E. Hoffer, W. C. Peebles and W. E. Dieter, ibid. 68 (1946) 1935.Google Scholar
  4. 4.
    A. L. Mackay, Mineral Mag. 32 (1960) 545.Google Scholar
  5. 5.
    K. J. Gallagher and D. N. Phillips, Chimia 23 (1969) 465.Google Scholar
  6. 6.
    J. Ellis, R. Giovanoli and W. Stumm, ibid. 30 (1976) 3.Google Scholar
  7. 7.
    K. M. Parida, J. Mater. Sci. 23 (1988) 1201.Google Scholar
  8. 8.
    T. Ishikawa and K. Inouye, Bull. Chem. Soc. Jpn 46 (1973) 2665.Google Scholar
  9. 9.
    Idem, ibid. 48 (1975) 1580.Google Scholar
  10. 10.
    R. H. H. Wolf, M. Wrischer and J. Sipalozuljevic, Kolloid Z. Z. Polym. 215 (1967) 57.Google Scholar
  11. 11.
    E. Matijević and P. Scheiner, J. Colloid Interface Sci. 63 (1978) 509.Google Scholar
  12. 12.
    E. Matijević and S. Ćimas, Colloid Polym. Sci. 265 (1987) 155.Google Scholar
  13. 13.
    C. M. Jr. Flynn, Chem. Rev. 84 (1984) 31.Google Scholar
  14. 14.
    K. Kandori, S. Uchida and T. Ishikawa, J. Mater. Sci., in press.Google Scholar
  15. 15.
    K. Kandori, M. Fukuoka and T. Ishikawa, ibid., 26 (1991) 3313.Google Scholar
  16. 16.
    T. Ishikawa and K. Inouye, Bull. Chem. Soc. Jpn 45 (1972) 2350.Google Scholar
  17. 17.
    A. Müller, Arzneinmittel Forsch. 17 (1967) 921.Google Scholar
  18. 18.
    T. Ishikawa, S. Nitta and S. Kondo, J. Chem. Soc. Farad. Trans, 1 82 (1986) 2401.Google Scholar
  19. 19.
    T. Ishikawa and K. Inouye, Bull. Chem. Soc. Jpn 46 (1973) 2665.Google Scholar
  20. 20.
    P. Pfeifer and D. Avnir, J. Chem. Phys. 79 (1983) 3558.Google Scholar

Copyright information

© Chapman & Hall 1992

Authors and Affiliations

  • T. Ishikawa
    • 1
  • T. Takeda
    • 1
  • K. Kandori
    • 1
  1. 1.School of ChemistryOsaka University of EducationOsakaJapan

Personalised recommendations