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Influence of alkali metal and ammonium cations on the structure of iron(II) and cobalt(III) hexacyanide complexes encapsulated in faujasite

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Abstract

Changing the cation composition (Na+ to K+, NH4 + Cs+) of faujasite with hexacyanoferrate(II) encapsulated in the large pores causes distortion of the octahedral symmetry of the complex.

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Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 30, No. 5, pp. 293–297, September–October, 1994.

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Gol'tsov, Y.G., Matkovskaya, L.A., Voloshinets, V.G. et al. Influence of alkali metal and ammonium cations on the structure of iron(II) and cobalt(III) hexacyanide complexes encapsulated in faujasite. Theor Exp Chem 30, 254–258 (1995). https://doi.org/10.1007/BF00536700

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  • DOI: https://doi.org/10.1007/BF00536700

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