Abstract
The mechanism and kinetics of vinyl chloride adsorption on cobalt-chromium catalyst were investigated by means of a response method, gravimetry, and IR spectroscopy. The mechanism of chemisorption of the chlorohydrocarbon consists of its oxidative decomposition and the formation of surface compounds with various bond strengths.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
V. M. Vlasenko, O. G. Chernitskii, O. V. Konopatskii, and V. L. Chernobrivets, Ukr. Khim. Zh., 59, No. 6, 584–588 (1993).
O. V. Konopatskii, V. M. Vlasenko, and O. G. Chernitskii, Teor. Éksp. Khim., 28, No. 3, 202–206 (1992).
O. V. Konopatskii, O. G. Chernitskii, and V. M. Vlasenko, Ékotekhnol. Resursosberezh., No. 5, 13–19 (1993).
O. V. Konopatskii, O. G. Chernitskii, and V. M. Vlasenko, Teor. Éksp. Khim., 29, No. 5, 449–455 (1993).
V. L. Ryabin, M. V. Kireev, and M. A. Berg (ed.), Inorganic Compounds of Chromium (Handbook) [in Russian], Khimiya, Leningrad (1981).
L. V. Sverdlov, M. A. Kovner, and E. P. Krainov, Vibrational Spectra of Monatomic Molecules [in Russian], Nauka, Moscow (1970).
A. A. Davydov, IR Spectroscopy in the Chemistry of Surface Oxides [in Russian], Nauka, Novosibirsk (1984).
K. G. Boreskov, Heterogeneous Catalysis [in Russian], Nauka, Moscow (1986).
Author information
Authors and Affiliations
Additional information
Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 30, No. 5, pp. 283–288, September–October, 1994.
Rights and permissions
About this article
Cite this article
Konopatskii, O.V., Chernitskii, O.G., Vlasenko, V.M. et al. Mechanism and kinetics of chemisorption of vinyl chloride on cobalt-chromium catalyst. Theor Exp Chem 30, 245–249 (1995). https://doi.org/10.1007/BF00536698
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00536698