Skip to main content
Log in

Influence of low-intensity electromagnetic field on autooscillations of concentration in belousov-zhabotinskii reaction

  • Published:
Theoretical and Experimental Chemistry Aims and scope

Abstract

A study has been made of the influence of an electromagnetic field (EMGF) with a frequency in the 40–60 GHz range and intensity up to 4–8 mW on autowaves of concentration in the reaction of sodium bromate (0.3 M), malonic acid (0.2 M), sulfuric acid (0.45 M), and Ferroin (0.003 M). It has been found that the action of the EMGF leads to decreases in the wavelength by amounts up to 26%. The experimentally measured temperature gradient created by the EMGF in a thin layer of the reaction mixture is no greater than 0.4°K. The value calculated for the solution temperature rise that is required to create the experimentally observed decrease in wavelength is 5–6° K. It is concluded, therefore, that the observed effect cannot be explained solely by thermal action of the EMGF through heating the reaction mixture.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

Literature cited

  1. A. M. Zhabotinskii, Concentration Autooscillations [in Russian], Nauka, Moscow (1974).

    Google Scholar 

  2. C. Walter, Enzyme Kinetics: Open and Closed Systems, Ronald Press, New York (1966).

    Google Scholar 

  3. A. T. Winfree, “Wavelike activity in biological and chemical media,” Lect. Notes Biomath., 2, 241–260 (1974).

    Google Scholar 

  4. I. Maselko, T. Tlaczala, M. Czerwinski, et al., “Oscillation reactions in the system: metabolites of Krebs cycle-manganese(2+)-potassium bromate-sulfuric acid,” Bioinorg. Chem., 2, No. 6, 529–536 (1978).

    Google Scholar 

  5. E. Koros, M. Burger, Z. Nagy, and M. Orban, “Oscillatory chemical reactions as models for studying bioprocesses,” Acta Pharm. Hung., 48, No. 4, 172–177 (1978).

    Google Scholar 

  6. T. R. Chay, “Oscillations in vesicular compartments,” Biophys. Chem., 13, No. 4, 325–328 (1981).

    Google Scholar 

  7. E. Sh. Ismailov, Biophysical Effect of Microwave Radiation [in Russian], Énergoatomizdat, Moscow (1987).

    Google Scholar 

  8. E. A. Andreev, M. U. Belyi, and S. P. Sit'ko, “Reaction of human organism to electromagnetic radiation in the millimeter range,” Vestn. Akad. Nauk Ukr. SSR, No. 1, 24–32 (1985).

    Google Scholar 

  9. A. S. Presman, Effects of Electromagnetic Fields on Living Organisms, Plenum Press, New York (1970).

    Google Scholar 

  10. L. P. Agulova, V. S. Kir'yanov, and A. M. Opalinskaya, “Change of fluctuation in Belousov-Zhabotinskii autooscillatory chemical reaction under the influence of a weak magnetic field,” Tomsk (1987); paper filed at VINITI, June 29, 1987, No. 3775-V87.

  11. M. L. Smoes, “Chemical waves in the oscillatory Zhabotinskii system. A transition from temporal to spatialtemporal organization,” in: Dynamic Synergetic Systems, Proceedings of the International Symposium on Synergetics, Bielefeld (1979); published in Berlin (1980), pp. 80–96.

  12. E. Koros, “Monomolecular treatment of chemical oscillation,” Nature, 251, No. 5477, 703–704 (1974).

    Google Scholar 

  13. M. J. Blandamer and D. L. Roberts, “Analysis of the dependence on temperature of the frequency of oscillation of the Belousov-Zhabotinskii reaction,” J. Chem. Soc., Faraday Trans. 1, 73, No. 7, 1056–1065 (1977).

    Google Scholar 

  14. L. Kuhnert, H.-J. Krug, and L. Pohlman, “Velocity of trigger waves and temperature dependence of autowave processes in the Belousov-Zhabotinskii reaction,” J. Phys. Chem., 89, No. 10, 2022–2026 (1985).

    Google Scholar 

  15. P. M. Wood and J. Ross, “A quantitative study of chemical waves and the Belousov-Zhabotinskii reaction,” J. Chem. Phys., 82, No. 4, 1924–1936 (1985).

    Google Scholar 

  16. A. S. Kovalenko, K. B. Yatsimirskii, L. N. Lugina, et al., “Influence of low-intensity electromagnetic radiation on concentration autowaves in Belousov-Zhabotinskii reaction,” Dokl. Akad. Nauk SSSR, 304, No. 5, 1143–1147 (1989).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 25, No. 6, pp. 704–709, November–December, 1989.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kovalenko, A.S., Lugina, L.N., Andreev, E.A. et al. Influence of low-intensity electromagnetic field on autooscillations of concentration in belousov-zhabotinskii reaction. Theor Exp Chem 25, 647–652 (1989). https://doi.org/10.1007/BF00534446

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00534446

Keywords

Navigation