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Reactions of polyhalopyridines 3. Reaction of heptachloro-2-picoline with hydrazine hydrate. structure of the 3,5,6-trichloro-4-hydrazino-2-trichloromethylpyridine molecule

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The reaction of heptachloropicoline with hydrazine hydrate has been studied. The formation of two isomers of hexachlorohydrazinopicoline was discovered corresponding to nucleophilic substitution at positions 2 and 4 of the pyridine ring. The structure of the isomers was determined with the aid of NMR spectroscopy and of x-ray structural analysis.

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Authors and Affiliations

  1. Chernogolovka Institute of Chemical Physics, 142432, Chernogolovka

    A. M. Sipyagin & Z. G. Aliev

Authors
  1. A. M. Sipyagin
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  2. Z. G. Aliev
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 11, 1495–1498, November, 1993.

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Sipyagin, A.M., Aliev, Z.G. Reactions of polyhalopyridines 3. Reaction of heptachloro-2-picoline with hydrazine hydrate. structure of the 3,5,6-trichloro-4-hydrazino-2-trichloromethylpyridine molecule. Chem Heterocycl Compd 29, 1287–1290 (1993). https://doi.org/10.1007/BF00532026

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  • DOI: https://doi.org/10.1007/BF00532026

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