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Diazabicycloalkanes with bridgehead nitrogen atoms

26. Reactions of hydroxyethyl benzo[b]-1,4-diazabicyclo[2.2.2]octenes

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

By heating 1-(2-hydroxyethyl)benzo[b]-1-azonium-4-azabicyclo-[2.2.2]octene halides in anhydrous solvents or via thermolysis, opening of the bicycle occurs with formation of the corresponding N-(2-hydroxyethyl)-N′-(2-haloethyl)-1, 2,3,4-tetrahydroquinoxalines. In the presence of base, fission of the hydroxyethyl group principally occurs.

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References

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Authors and Affiliations

  1. Institute of Bioorganic Chemistry, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk

    S. O. Doronina, A. A. Gall' & G. V. Shishkin

Authors
  1. S. O. Doronina
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  2. A. A. Gall'
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  3. G. V. Shishkin
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Additional information

For Communication 25, see [1].

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 8, pp. 1091–1094, August, 1992.

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Doronina, S.O., Gall', A.A. & Shishkin, G.V. Diazabicycloalkanes with bridgehead nitrogen atoms. Chem Heterocycl Compd 28, 917–920 (1992). https://doi.org/10.1007/BF00531326

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  • DOI: https://doi.org/10.1007/BF00531326

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