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Promotion by oxygen of the formation of methanol and dimethyl ether during the hydrogenation of CO over supported palladium catalysts

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Abstract

Addition of a small amount of oxygen to synthesis gas promotes the formation of oxygen-containing compounds (methanol, dimethyl ether) during the hydrogénation of CO over palladium supported on zirconium, aluminum, magnesium, lanthanum, and silicon oxides. The maximum effect on the rate of formation of oxygen-containing compounds was observed with 0.5–2.0 vol.% of oxygen in synthesis gas.

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Authors and Affiliations

  1. L. V. Pisarzhevskii Institute of Physical Chemistry, Ukrainian Academy of Sciences, Kiev

    G. V. Filonenko, T. M. Shaprinskaya, Yu. I. Pyatnitskii, V. P. Stasevich & V. I. Gritsenko

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  1. G. V. Filonenko
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  2. T. M. Shaprinskaya
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  3. Yu. I. Pyatnitskii
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  4. V. P. Stasevich
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  5. V. I. Gritsenko
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Translated from Teoreticheskaya Éksperimental'naya Khimiya, Vol. 28, No. 4, pp. 359–363, July–August, 1992.

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Filonenko, G.V., Shaprinskaya, T.M., Pyatnitskii, Y.I. et al. Promotion by oxygen of the formation of methanol and dimethyl ether during the hydrogenation of CO over supported palladium catalysts. Theor Exp Chem 28, 280–283 (1993). https://doi.org/10.1007/BF00530290

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  • DOI: https://doi.org/10.1007/BF00530290

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