Abstract
The concept of ionic character in σ and π bond systems is considered in the light of recent definitions of orbital electronegativity [6, 14].
Résumé
Le caractère ionique des liaisons σ et π est discuté en tenant compte des définitions récentes de l'électronégativité des orbitales.
Zusammenfassung
Das Konzept des ionischen Charakters in σ und π Bindungen wird im Lichte neuerer Definitionen von Orbitalelektronegativitäten diskutiert.
Similar content being viewed by others
References
Ferreira, R.: Trans. Faraday. Soc. 59, 1064, 1075 (1963).
Fraga, S., and B. J. Ransil: J. chem. Physics 34, 727 (1961).
Gordy, W.: Discussions of Faraday Soc. 19, 14 (1955).
Hannay, N. B., and C. P. Smyth: J. Amer. chem. Soc. 68, 171 (1946).
Hinze, J., and H. H. Jaffe: J. Amer. chem. Soc. 84, 540 (1962).
—, M. A. Whitehead, and H. H. Jaffe: J. Amer. chem. Soc. 85, 148 (1963).
Iczkowski, R. P., and J. L. Margrave: J. Amer. chem. Soc. 83, 3547 (1961).
Lakatos, B.: Z. Electrochem. 61, 944 (1957).
Mulliken, R. S.: J. chem. Physics 23, 1833, 1841, 2338, 2343 (1955).
Pauling, L.: “Nature of Chemical Bond”, Cornell U.P. 1948 2nd Edition P. 64, 70.
Pritchard, H. O.: J. Amer. chem. Soc. 85, 1876 (1963).
Sanderson, R. T.: J. Amer. chem. Soc. 74, 272 (1952).
Whitehead, M. A.: J. chem. Physics 36, 3006 (1962).
—, and H. H. Jaffe: Theoret. Chim. Acta. (Berl.) 1, 209 (1963).
Author information
Authors and Affiliations
Additional information
We wish to acknowledge financial support from the National Research Council of Canada. One of us (N.C.B.) thanks the council for the award of a studentship.
Rights and permissions
About this article
Cite this article
Baird, N.C., Whitehead, M.A. Ionic character. Theoret. Chim. Acta 2, 259–264 (1964). https://doi.org/10.1007/BF00527052
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00527052