Abstract
The theory of multiphonon processes is applied to the broad optical absorption bands of [PtCl4]2-. It is found that the width and the temperature dependence of the peak position are explained by interaction of the electron with intramolecular vibrations.
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We are indebted to Yu. E. Perlin, I. B. Bersuker, E. V. Vitiu, and B. S. Tsukerblat for valuable discussions.
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Kovarskaya, B.P., Kovarskii, V.A. Shape of the optical absorption line in planar square complexes of [PtCl4]2- type. Theor Exp Chem 4, 511–516 (1971). https://doi.org/10.1007/BF00527030
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DOI: https://doi.org/10.1007/BF00527030