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Some problems of the thermodynamics of intermolecular interaction

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Abstract

The significance of the condition that temperature and volume should be constant for thermodynamic description of interaction has been shown. A postulate concerning the potential energy of interaction ε and the potential barrier ϕ in relation to ε has been obtained. These functions characterize directly the interaction in real thermodynamic systems. On this basis it has been possible to consider a wide range of problems and to obtain a number of new results (a general compensation effect for liquids and solutions, an equation for the critical point, etc.).

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Authors and Affiliations

  1. Institute of Organic Chemistry, Siberian Division AS USSR, Novosibirsk

    E. S. Rudakov

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  1. E. S. Rudakov
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Rudakov, E.S. Some problems of the thermodynamics of intermolecular interaction. Theor Exp Chem 2, 34–39 (1967). https://doi.org/10.1007/BF00524254

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  • DOI: https://doi.org/10.1007/BF00524254

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