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Synthesis of bis(o-hydroxyphenyl)-1,3,5-triazines, 1,2,4-triazoles, and oxadiazole by recyclization of the o-hydroxyphenyl-4-oxo-1,3-benzoxazinium cation

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The acidic cyclization of disalicylamide gave 2-(o-hydroxyphenyl)- and 2-(o-acetoxyphenyl)-4-oxo-1,3-benzoxazinium perchlorates, by reaction of which with hydroxylamine, hydrazines, benzamidine, guanidines, and S-methylisothiourea bis(o-hydroxyphenyl)-1,2,4-oxadiazole, triazoles, and sym-triazines were synthesized. Mono- and bis (o-acetoxyphenyl) triazoles were obtained.

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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 3, pp. 406–410, March, 1983.

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Ryabukhin, Y.I., Faleeva, L.N. & Korobkova, V.G. Synthesis of bis(o-hydroxyphenyl)-1,3,5-triazines, 1,2,4-triazoles, and oxadiazole by recyclization of the o-hydroxyphenyl-4-oxo-1,3-benzoxazinium cation. Chem Heterocycl Compd 19, 332–336 (1983). https://doi.org/10.1007/BF00513273

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  • DOI: https://doi.org/10.1007/BF00513273

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