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Electrochemical oxidation of substituted 3,4-dihydro-2-pyridones at a rotating graphite electrode with a ring

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

Using the method of a rotating disk (graphite) electrode with a ring, UV spectroscopy, and prolonged electrolysis, it has been shown that the first stage of the electrochemical oxidation of substituted 3,4-dihydro-2-pyridones in anhydrous acetonitrile corresponds to a two-electron process taking place by an ECE mechanism and leads to the formation of the corresponding substituted 2-pyridones. The potentials of the electrochemical oxidation of the 3-cyano and 3-carbamoyl derivatives of the reduced forms and the potentials of the electroreduction of the corresponding oxidized compounds have been determined.

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Authors and Affiliations

  1. Institute of Organic Synthesis, Academy of Sciences of Latvian SSR, Riga

    V. P. Kadysh, Ya. P. Stradyn', Ya. V. Ogle, Yu. É. Pelcher & G. Ya. Dubur

Authors
  1. V. P. Kadysh
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  2. Ya. P. Stradyn'
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  3. Ya. V. Ogle
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  4. Yu. É. Pelcher
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  5. G. Ya. Dubur
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Additional information

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 1, pp. 87–91, January, 1984.

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Kadysh, V.P., Stradyn', Y.P., Ogle, Y.V. et al. Electrochemical oxidation of substituted 3,4-dihydro-2-pyridones at a rotating graphite electrode with a ring. Chem Heterocycl Compd 20, 73–77 (1984). https://doi.org/10.1007/BF00505855

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  • DOI: https://doi.org/10.1007/BF00505855

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