Abstract
High-pressure viscosities and densities of n-butane, n-pentane, n-hexane, and n-octane have been measured with a specially designed falling cylinder viscometer. Data cover the pressure range from 10 to 70 MPa at temperatures from 310 to 450 K. When the viscosity is plotted as a function of density, the data at all temperatures and pressures are shown to reduce to a single curve for each alkane. An exponential relationship of the form η = B 1 x exp(B 2xρ) + B 3 is used to describe the density dependence of viscosity. The logarithmic viscosity of the alkanes changes linearly with the inverse temperature at all pressures. The density shows a linear dependence on temperature.
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References
K. Stephan and K. Lucas, Viscosity of Dense Fluids (Plenum Press, New York, 1979).
P. E. Liley, T. Makita, and Y. Tanaka, in Properties of Inorganic and Organic Fluids, C. Y. Ho, ed. (Hemisphere, New York, 1988).
H. Kashiwagi and T. Makita, Int. J. Thermophys. 3:289 (1982).
D. W. Brazier and G. R. Freeman, Can. J. Chem. 47:893 (1969).
N. A. Agaev and I. F. Golubev, Gazov. Promst. 8:50 (1963).
P. W. Bridgman, Proc. Am. Acad. Arts Sci. 61:57 (1926).
J. H. Dymond and K. J. Young, Int. J. Thermophys. 1:331 (1980).
J. H. Dymond, J. Robertson, and J. D. Isdale, Int. J. Thermophys. 2:133 (1981).
E. Dickinson, J. Phys. Chem. 81:2108 (1977).
N. A. Agaev and I. F. Golubev, Doklady Akademii Nauk SSSR 151:597 (1963).
Ya. M. Naziev, S. O. Guseinov, and A. K. Akhmedov, Neft. Gazov. Promst. 15:65 (1972).
J. H. Dymond, K. J. Young, and J. D. Isdale, Int. J. Thermophys. 1:345 (1980).
D. A. Berstad, Viscosity and Density of n-Hexane, Cyclohexane and Benzene, and Their Binary Mixtures with Methane, Ph.D. thesis (Universitetet I Trondheim, Norway, 1989).
J. H. Dymond and K. J. Young, J. Chem. Thermodynam. 11:887 (1979).
R. G. Griskey and L. N. Canjar, AIChE J. 5:29 (1959).
D. E. Stewart, B. H. Sage, and W. N. Lacey, Ind. Eng. Chem. 46:2529 (1954).
S. E. Babb and G. J. Scott, J. Chem. Phys. 40:3666 (1964).
H. H. Reamer, G. Cokelet, and B. H. Sage, Anal. Chem. 31:1422 (1959).
A. L. Lee and R. T. Ellington, J. Chem. Eng. Data 10:101 (1965).
N. A. Agaev and I. F. Golubev, Gazov. Promst. 8:45 (1963).
A. F. Collings and E. McLaughlin, Trans. Faraday Soc. 67:340 (1971).
B. H. Sage and W. N. Lacey, Thermodynamic Properties of the Lighter Paraffin Hydrocarbons and Nitrogen (American Petroleum Institute, New York, 1950).
J. P. Dolan, K. E. Starling, A. L. Lee, B. E. Eakin, and R. T. Ellington, J. Chem. Eng. Data 8:396 (1963).
L. T. Carmichael and B. H. Sage, J. Chem. Eng. Data 8:612 (1963).
D. E. Diller and L. J. Van Poolen, Int. J. Thermophys. 6:43 (1985).
Patent application being processed.
J. B. Irwing and A. J. Barlow, J. Phys. E. Sci. Intr. 4:232 (1971).
J. B. Irwing, J. Phys. D Appl. Phys. 5:214 (1972).
R. J. McLachlan, J. Phys. E Sci. Inst. 9:391 (1976).
Y. L. Sen and E. Kiran, Polym. Preprints 31(1):556 (1990).
Y. L. Sen and E. Kiran, J. Supercrit. Fluids 3:91 (1990).
F. D. Harvey, Engineering Properties of Steel (American Society for Metals, Ohio, 1982).
R. C. Reid, J. M. Prausnitz, and B. E. Poling, The Properties of Gases and Liquids, 4th ed. (McGraw-Hill, New York, 1987).
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Kiran, E., Sen, Y.L. High-pressure viscosity and density of n-alkanes. Int J Thermophys 13, 411–442 (1992). https://doi.org/10.1007/BF00503880
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DOI: https://doi.org/10.1007/BF00503880