Abstract
A vibrating-wire apparatus was used to measure liquid density and viscosity simultaneously under high-temperature conditions. Densities and viscosities were measured along 11 isotherms at temperatures from (298.15 to 548.15) K and pressures up to 10 MPa for n-dodecane, and over a temperature range of (303.15 to 548.15) K and at equilibrium pressures up to about 6 MPa for carbon dioxide + n-dodecane. The estimated combined expanded uncertainties are 0.24 % for density and 2.2 % for viscosity with a confidence level of 0.95 (k = 2). In addition, experimental density and viscosity data were correlated with the modified Tait equation and Tait–Andrade equation, respectively, and comparisons with literature data were made. With regard to n-dodecane, the equations present both literature data and our experimental results with deviations almost within 0.2 % for density, and 3.0 % for viscosity. For simplicity, the experimental data of carbon dioxide + n-dodecane were correlated using these two Tait-like equations directly without considering the mole fraction of CO2. Both correlations describe our measured data of carbon dioxide + n-dodecane almost within 0.2 % for density and 1 % for viscosity.
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The authors acknowledge the financial support of the National Natural Science Foundation of China (Nos. 51761135116 and 51976164).
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XL: Experiment, Writing—original draft; JY: Analysis, Writing—review and editing; XM: Supervision, Writing—review and editing; JW: Supervision, Writing—review and editing, Project administration.
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Liang, X., Yang, J., Meng, X. et al. Density and Viscosity Measurements of n-Dodecane and Carbon Dioxide + n-Dodecane at Temperatures from (298 to 548) K. Int J Thermophys 44, 52 (2023). https://doi.org/10.1007/s10765-022-03148-0
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DOI: https://doi.org/10.1007/s10765-022-03148-0