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Effect of electron impact on 9-phenylacridines

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The high intensities of the molecular-ion peaks in the mass spectra of 9-phenylacridines, the absence of ions characterizing cleavage of the interannular bond, and the high selectivity of the fragmentation constitute evidence for the presence of conjugation between the aromatic rings of the system. Dehydrogenation processes during electron impact that lead to the formation of condensed systems are peculiar to the investigated compounds. Unique detachment of an amino group from the (M-H)+ ion was noted for 9-(4-aminophenyl)acridines.

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Literature cited

  1. R. M. Acheson, Acridities, New York (1956), p. 99.

  2. N. F. Kazarinova and I. Ya. Postovskii, Zh. Obshch. Khim., 27, 3325 (1957).

    Google Scholar 

  3. W. Seiffert, V. Zanker, and H. Mantsch, Tetrahedron Lett., 4304 (1968).

  4. G. S. Sakovieh, V. N. Konyukhov, T. A. Bandurina, Z. V. Pushkareva, G. N. Koltun, V. F. Degtyarev, V. E. Blokhin, M. A. Presnov, A. L. Konovalova, and A. S. Barybin, Khim.-Farmats. Zh., No. 3, 17 (1973).

    Google Scholar 

  5. R. A. Khmel'nitskii, V. I. Vysotskii, I. I. Grandberg, A. N. Kost, and V. A. Bulin, Zh. Organ. Khim., 7, 1514 (1971).

    Google Scholar 

  6. R. Engel, D. Halpern, and B.-A. Funk, Org. Mass Spectrom., 7, 177 (1973).

    Google Scholar 

  7. O. N. Chupakhin, Yu. N. Sheinker, Z. V. Pushkareva, V. A. Trofimov, E. G. Kovalev, and V. G. Kharchuk, Khim. Geterotsikl. Soedin., 535 (1973).

  8. P. N. Rylander, S. Meyerson, E. L. Eliel, and I. D. Molollum, J. Amer. Chem. Soc., 85, 2723 (1963).

    Google Scholar 

  9. A. V. Robertson and C. Djerassi, J. Amer. Chem. Soc., 90, 6992 (1968).

    Google Scholar 

  10. A. Berntsen, Ber., 16, 767 (1883).

    Google Scholar 

  11. V. L. Rusinov, O. N. Chupakhin, V. A. Trofimov, M. N. Kollegova, and I. Ya. Postovskii, Khim. Geterotsikl. Soedin., 216 (1972).

  12. A. Berntsen, Ann., 224. 1 (1884).

    Google Scholar 

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Authors and Affiliations

  1. S. M. Kirov Ural Polytechnic Institute, Sverdlovsk. K. A. Timiryazev Agricultural Academy, Moscow

    N. A. Klyuev, R. A. Khmel'nitskii, O. N. Chupakhin, G. A. Mal'tseva, V. L. Rusinov & I. Ya. Postovskii

Authors
  1. N. A. Klyuev
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  2. R. A. Khmel'nitskii
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  3. O. N. Chupakhin
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  4. G. A. Mal'tseva
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  5. V. L. Rusinov
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  6. I. Ya. Postovskii
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Additional information

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 7, pp. 983–986, July, 1975.

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Klyuev, N.A., Khmel'nitskii, R.A., Chupakhin, O.N. et al. Effect of electron impact on 9-phenylacridines. Chem Heterocycl Compd 11, 862–865 (1975). https://doi.org/10.1007/BF00497314

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  • DOI: https://doi.org/10.1007/BF00497314

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