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A method for the quantitative decomposition of cluster compounds and the determination of rhodium and ruthenium by flame atomic absorption spectrometry

Quantitative Aufspaltung von Clusterverbindungen und Bestimmung von Rhodium und Ruthenium durch Flammen-AAS

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  • Elemental Analyses by AAS
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Summary

Single crystals of cluster compounds were decomposed with two different methods. The hydrogen peroxide method is easy to use and no special equipments are needed. The autoclave method has proved to be more effective and led to the complete decomposition of all tested cluster compounds. Buffering with lanthanum sulphate or KHSO4 was used to eliminate interferences caused by foreign metal ions and phosphorus. Results of measurements after decomposition of the cluster compounds with the two methods are shown.

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References

  1. Wilkinson G, Stone FGA, Abel GW (1982) Comprehensive organometallic chemistry, vol 6. Pergamon, Oxford, p 376

    Google Scholar 

  2. Beamish FE, Van Loon JC (1977) Analysis of noble metals. Academic Press, New York

    Google Scholar 

  3. Wichers E, Schlecht WG, Gordon CL (1944) J Res Nat Bur Stand 33:363

    Google Scholar 

  4. Van Loon JC, Szeto MS, Howson WW, Levin IA (1984) At Spectrosc 5:43

    Google Scholar 

  5. Belyaev VN, Vladimirskaya IN, Kolonina LN, Kovalev GG, Kuznetsov LB, Shiryaeva OA (1985) J Anal Chem USSR 40:135

    Google Scholar 

  6. Rigin VI, Eremina AO (1984) J Anal Chem USSR 39:408

    Google Scholar 

  7. Pursiainen J, Pakkanen TA, Heaton BT, Seregni C, Goodfellow RG (1986) J Chem Soc Dalton Trans, pp 681

  8. Pursiainen J, Pakkanen TA, Jääskeläinen J (1985) J Organomet Chem 290:85

    Google Scholar 

  9. Pursiainen J, Pakkanen TA, Smolander K (1987) J Chem Soc Dalton Trans, p 781

  10. Yawney DBW, Stone FGA (1969) J Chem Soc A, p 502

  11. Venäläinen T, Pakkanen TA (1984) J Organomet Chem 266:269

    Google Scholar 

  12. Venäläinen T, Pakkanen TA (1986) J Organomet Chem 316:183

    Google Scholar 

  13. Bruce MI, Kehoe DC, Malisons JG, Nicholson BK, Rieger PH, Williams WL (1982) J Chem Soc Chem Commun, p 442

  14. Garska KJ (1976) At Absorpt Newsl 15:38

    Google Scholar 

  15. Atwell GM, Hebert JY (1969) Appl Spectrosc 23:480

    Google Scholar 

  16. Jahnssen A, Umlaud F (1970) Fresenius Z Anal Chem 251:101

    Google Scholar 

  17. Makarov DF, Kukushkin YuN, Eroshevich TA (1974) J Anal Chem USSR 29:1829

    Google Scholar 

  18. Apolitskii VN, Yudina LP, Latysheva YuP, Pronin VA (1975) J Anal Chem USSR 30:141

    Google Scholar 

  19. Schnapfe MM, Grimaldi FS (1969) Talanta 16:1461

    Google Scholar 

  20. El-Defrawy MM, Posta J, Beck MT (1978) Anal Chim Acta 102:185

    Google Scholar 

  21. Pursiainen J, Ahlgren M, Pakkanen TA (1985) J Organomet Chem 297:391

    Google Scholar 

Download references

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Authors and Affiliations

  1. Department of Chemistry, University of Joensuu, P.O. Box 111, SF-90101, Joensuu, Finland

    K. Smolander, I. Mustonen, J. Pursiainen, T. Saari, T. Venäläinen & T. A. Pakkanen

Authors
  1. K. Smolander
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  2. I. Mustonen
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  3. J. Pursiainen
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  4. T. Saari
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  5. T. Venäläinen
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  6. T. A. Pakkanen
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Smolander, K., Mustonen, I., Pursiainen, J. et al. A method for the quantitative decomposition of cluster compounds and the determination of rhodium and ruthenium by flame atomic absorption spectrometry. Z. Anal. Chem. 329, 27–30 (1987). https://doi.org/10.1007/BF00487535

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  • DOI: https://doi.org/10.1007/BF00487535

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