Skip to main content
SpringerLink
Log in

Hydrolysis of esters of certain substitutes of 1,3,5-triazine

  • Published:
Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The mechanism of hydrolysis of esters of triazine substitutes was studied. It was shown that hydrolysis of l-menthyl esters in both alkaline and acid media at 80–120° C takes place with cleavage of the bond between the oxygen and carbon of triazine. The bond between the oxygen and carbon of alcohol is broken at 180–200° C in acid medium. The kinetics of alkaline hydrolysis of triazine esters was studied, and it was established that the stability of the latter increases in relation to the influence of the substitute in triazine in the order: C6H5 < NHC6H5 < NHC2H5 < N(C2H5)2. A number of new C-substitutes of triazine was synthesized.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. V. I. Mur, Usp. khim., 33, 182, 1964.

    Google Scholar 

  2. M. A. Chekalin, ZhVKhO [Mendeleev Chemistry Journal], 11, 43, 1966.

    Google Scholar 

  3. V. I. Mur, Vestn. tekhn. i ekonom. inform., 9, 32, 1963.

    Google Scholar 

  4. V. I. Mur. Zh. A. Gorbunova, and A. I. Korolev, ZhVKhO, 6, 586, 1961; 8, 235, 1963.

    Google Scholar 

  5. Ya. K. Syrkin, Izv. AN SSSR, OKhN, 3, 401, 1959.

    Google Scholar 

  6. Ya. K. Syrkin, and I. I. Moiseev, Usp. khim., 27, 717, 1958.

    Google Scholar 

  7. Zh. A. Bedina, Candidate's dissertation [in Russian], Moscow, 1964.

  8. W. Hückel and W. Tappe, Ann., 537, 113, 1939.

    Google Scholar 

  9. G. V. Pigulevskii, Chemistry of Terpenes [in Russian], Izd. LGU, p. 94, 1949.

    Google Scholar 

  10. J. P. Thurston, F. C. Schafer, J. R. Dudley, and D. Holm-Hansen, J. Am. Chem. Soc., 73, 2992, 1951.

    Google Scholar 

  11. W. M. Pearlmann and C. K. Banks, J. Am. Chem. Soc., 70, 3726, 1948.

    Google Scholar 

  12. R. K. Bair and C. M. Suter, J. Am. Chem. Soc., 64, 1978, 1942.

    Google Scholar 

  13. L. A. Chugaev, ZhRFKhO, 35, 1117, 1903.

    Google Scholar 

  14. R. Hirt, H. Nidecker, and R. Berchtold, Helv. Chim. Acta, 33, 1365, 1950.

    Google Scholar 

  15. V. I. Mur, ZhOKh, 29, 2267, 1959.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Scientific-Research Institute for Organic Intermediates and Dyes, Moscow

    V. I. Mur & Zh. A. Bedina

Authors
  1. V. I. Mur
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Zh. A. Bedina
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

We thank Prof. A. I. Korolev for the proposal, and the attention he gave to this work.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Mur, V.I., Bedina, Z.A. Hydrolysis of esters of certain substitutes of 1,3,5-triazine. Chem Heterocycl Compd 4, 814–816 (1968). https://doi.org/10.1007/BF00486972

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00486972

Keywords

Search

Navigation