Abstract
Alkylidene derivatives of 2-aminoethylhydrazines exist in solutions either as 2-aminoethylhydrazones or as the ring-chain tautomeric mixtures of the hydrazone—perhydro-1,2,4-triazine depending on the structure. The oxidation of perhydro-1,2,4-triazines leads to the formation of 2,3,4,5-tetrahydro-1,2,4-triazines.
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Literature Cited
A. A. Potekhin, V. A. Dokichev, and L. V. Solov'eva, Zh. Org. Khim., 26, 537 (1990).
P. S. Lobanov, O. V. Solod, and A. A. Potekhin, Zh. Org. Khim., 19, 2310 (1983).
P. S. Lobanov, A. N. Poltorak, and A. A. Potekhin, Zh. Org. Khim., 14, 1086 (1978).
Yu. Yu. Samitov, Khim. Geterotsikl. Soedin., No. 12, 1587 (1978).
R. é. Valter, Ring-Chain Isomerism in Organic Chemistry [in Russian], Zinatne, Riga (1978), p. 135.
B. V. Ioffe, M. A. Kuznetsov, and A. A. Potekhin, The Chemistry of Organic Derivatives of Hydrazine [in Russian], Khimiya, Leningrad (1979), p. 187.
S. M. Shevchenko and A. A. Potekhin, Khim. Geterotsikl. Soedin., No. 12, 1637 (1979).
A. A. Potekhin, S. M. Shevchenko, T. Ya. Vakhitov, and V.A. Gindin, Khim. Geterotsikl. Soedin., No. 9, 1217 (1981).
J. Ropenga and S. Grudzinski, Acta Polon. Pharm., 34, 391 (1977).
C. J. Overberger, J.-P. Anselm, and J. G. Lombardino, Organic Compounds with Nitrogen-Nitrogen Bonds [Russian translation], Khimiya, Leningrad (1970), p. 18.
D. S. Santilli and P. B. Dervan, J. Am. Chem. Soc., 101, 2317 (1979)
V. A. Surnin, I. G. Zenkevich, P. S. Lobanov, and A. A. Potekhin, Zh. Org. Khim., 19, 2288 (1983).
S. Grudzinski, A. Kotelko, and J. Strumillo, Acta Polon. Pharm., 26, 217 (1969).
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For Communication 21, see [1].
Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 10, pp. 1392–1396, October, 1991.
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Lobanov, P.S., Sarafanova, L.A. & Potekhin, A.A. Ring-chain tautomerism of substituted hydrazones. 22. Synthesis, structure, and oxidation of alkylidene derivatives of 2-aminoethylhydrazines. Chem Heterocycl Compd 27, 1120–1124 (1991). https://doi.org/10.1007/BF00486810
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DOI: https://doi.org/10.1007/BF00486810