Abstract
6-Bromo-N-methylpyridone reacts with phosphorus pentachloride at 180° C to form, 2, 6-dichloroanthrapyridine. The latter reacts with amines at moderate temperatures forming 6-amino-2-chloro derivatives of anthrapyridine and at high temperatures forming 2, 6-diamino-substituted anthrapyridines.
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S. I. Popov, T. N. Kurdyumova, and N. S. Dokunikhin, KhGS [Chemistry of Heterocyclic Compounds], 2, 254, 1966.
German patent no. 256297, Zbl., I, 758, 1913. 1913.
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For part III, see [1].
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Popov, S.I., Kurdyumova, T.N. & Dokunikhin, N.S. Investigations in the field of anthrapyridone. Chem Heterocycl Compd 4, 496–498 (1971). https://doi.org/10.1007/BF00486769
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DOI: https://doi.org/10.1007/BF00486769