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Polyoxometallates based macromolecules

Code: BP9

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Abstract

The synthesis of polyoxometallates based macromolecules P n (P=[SiW11O40(SiR)2]4−.4Bu4N+) presenting interesting physical properties (electrochemistry, photochemistry) is detailed. Three different paths are described, organic polymerization of monomers P (R = vinyl, allyl, methacryl, styryl), hydrosilation of monomers (R=H, R′=vinyl) or direct synthesis of polymeric species. These different polymers are characterized from a multi spectroscopic study (IR, NMR), and scattering experiments (QELS, SAXS). Reaction conditions influence both the polymerization yield, the size, the structure, and the properties of these organic-inorganic hybrids.

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Authors and Affiliations

  1. Laboratoire de Chimie Structurale Organique (URA 1384), Université Paris-Sud, Bât. 420, 91405, Orsay Cedex, France

    P. Judeinstein

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  1. P. Judeinstein
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Judeinstein, P. Polyoxometallates based macromolecules. J Sol-Gel Sci Technol 2, 147–151 (1994). https://doi.org/10.1007/BF00486230

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  • DOI: https://doi.org/10.1007/BF00486230

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