Summary
A rapid method for the speciation of mercury in fish has been described. Organomercurials in benzene extract were separated by glass capillary gas chromatography and detected by atomic absorption spectrometry. Spiked alkylmercury in fish yielded 95% recovery with one single extraction with benzene. The absolute detection limit was about 1.0×10−10 g mercury. The method can be applied to the determination of 0.04 ppm of mercury in a 0.5 g sample.
Similar content being viewed by others
References
Westoo G (1966) Acta Chem Scand 20:2131
Johansson G, Ryhage R, Westoo G (1970) Acta Chem Scand 24:2349
Hunter D (1969) The diseases of occupations, 4th edn. Little, Brown and Co., Boston, Mass., p 289
Westoo G (1967) Acta Chem Scand 21:1790
Westoo G (1968) Acta Chem Scand 22:2277
Uthe JF, Solomon J, Grift B (1972) J Assoc Off Anal Chem 55:585
Kamps LR, McMahon B (1972) J Assoc Off Anal Chem 55:590
Schafer ML, Rhea U, Peeler JT, Hamilton CH, Campbill JE (1975) J Agric Food Chem 23:1079
Coppon CJ, Smith JC (1977) Anal Chem 49:365
Longbottom JE, Dressman RC, Lichtenberg JJ (1972) J Assoc Off Anal Chem 55:583
Longbottom JE (1972) Anal Chem 40:1111
Tatton J O'G, Wagstaffe PJ (1969) J Chromatogr 44:284
Gonzaloz JG, Ross RT (1972) Anal Lett 5:683
Bye R, Paus Per E (1979) Anal Chim Acta 107:169
Newsome WH (1971) J Agric Food Chem 19:567
Fillippelli M (1987) Anal Chem 59:116
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Gui-bin, J., Zhe-ming, N., Shun-rong, W. et al. Organic mercury speciation in fish by capillary gas chromatography interfaced with atomic absorption spectrometry. Z. Anal. Chem. 334, 27–30 (1989). https://doi.org/10.1007/BF00481966
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00481966