Abstract
A method was developed for obtaining the heteroanalogs of steroidal 8-azagonanes using intermediate organoboron compounds with a boron-oxygen bond or esters of boric acid. 8-Azagona-1,3,5(10)-triene, D-homo-8-azagona-1,3,5(10)-triene, and D-dihomo-8-azagona-1,3,5(10)-triene were synthesized.
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Translated from Khimiya Geterotsiklicheskhikh Soedinenii, No. 11, pp. 1483–1485, November, 1989.
The authors thank N. N. Chichelova for the 1,5-diketones, which were synthesized in the department of organic chemistry of Vladivostok State University.
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Gertsev, V.V., Romanov, Y.A. Organoboron method for the synthesis of 8-azagonanes. Chem Heterocycl Compd 25, 1239–1241 (1989). https://doi.org/10.1007/BF00481517
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DOI: https://doi.org/10.1007/BF00481517