Abstract
The addition of phthalimidonitrene with phenylbutenynes proceeds exclusively at the double bond and leads to derivatives of 1-phthalimido-2-ethynylaziridine in high yield. The observed chemoselectivity of this reaction is attributed to the anti-aromatic transition state in the case of the addition of phthalimidonitrene to the triple bond.
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 2, pp. 173–179, February, 1989.
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Kuznetsov, M.A., Semenovskii, V.V., Belov, V.N. et al. Reaction of phthalimidonitrene with phenylbutenynes. Chem Heterocycl Compd 25, 136–142 (1989). https://doi.org/10.1007/BF00479905
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DOI: https://doi.org/10.1007/BF00479905