Skip to main content
SpringerLink
Log in

Electron density distribution in heterocyclic systems with two adjacent nitrogen atoms

IV. Dipole moments of some 1, 2, 4-tria zole derivatives

  • Published:
Chemistry of Heterocyclic Compounds Aims and scope

Abstract

A comparison is given between the dipole moments found experimentally for 1, 2, 4-triazole and its derivatives and those computed vectorially. In 1, 2, 4-triazoles unsubstituted on nitrogen, the hydrogen is attached at N1 in the majority of cases. The 1, 2, 4-triazoles undergo acylation on N1. Under the influence of a strong electron acceptor (a p-nitrophenyl substituent), the electron cloud of the triazole ring is highly polarized.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. S. A. Hiller, I. B. Mazheika, and I. I. Grandberg, KhGS [Chemistry of Heterocyclic Compounds], 107, 1965.

  2. S. A. Hiller, I. B. Mazheika, and I. I. Grandberg, KhGS [Chemistry of Heterocyclic Compounds], 103, 1965.

  3. I. Mazheika, L. Avota, G. Sokolov, and S. Hiller, ZhOKh, 34, 3380, 1964.

    Google Scholar 

  4. K. T. Potts, Chem. Rev., 61, 87, 1961.

    Google Scholar 

  5. A. R. Katritzky and J. M. Lagowski, Advances in Heterocyclic Chemistry, New York-London, vol. 2, 1963.

  6. M. R. Atkinson and J. B. Polya, J. Chem. Soc., 3319, 1954.

  7. M. R. Atkinson and J. B. Polya, J. Chem. Soc., 141, 1954.

  8. K. A. Jensen and A. Friediger, Kgl. Danske Videnskab. Selskab. Mat. fys. med., 20, no. 20, 1943.

  9. D. W. Kaiser and C. A. Peters, J. Org. Chem., 18, 196, 1953.

    Google Scholar 

  10. Ya. A. Levin, Studies in the Field of 1, 2, 4-Triazolo-[a] pyrimidines [in Russian], author's abstract of dissertation, Kazan, 1963.

  11. C. P. Smyth, Dielectric Behavior and Structure, New York, Toronto, London, 293, 1955.

  12. O. A. Osipov, A. M. Simonov, V. I. Minkin, and A. D. Garnovskii, ZhFKh, 36, 1466, 1962.

    Google Scholar 

  13. G. I. Chipen, V. Ya. Grinshtein, and M. B. Tiltin'sh, Izv. AN Latv. SSR, Ser. Khim., 393, 1962.

  14. G. I. Chipen and V. Ya. Grinshtein, Izv. AN Latv. SSR, Ser. Khim., 401, 1962.

  15. G. I. Chipen and V. Ya. Grinshtein, Izv. AN Latv. SSR, Ser. Khim., 411, 1962.

  16. G. I. Chipen, V. Ya. Grinshtein, and A. K. Grinvalde, Izv. AN Latv. SSR, Ser. Khim., 495, 1962.

  17. G. I. Chipen and V. Ya. Grinshtein, ZhOKh, 32, 460, 1962.

    Google Scholar 

  18. G. I. Chipen, Ya. A. Eidus, and Ya. S. Bobovich, ZhSKh, 6, 53, 1965.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Organic Synthesis AS Latvian SSR, Riga

    I. B. Mazheika, G. I. Chipen & S. A. Hiller

Authors
  1. I. B. Mazheika
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. G. I. Chipen
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. S. A. Hiller
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

For communication III see [1].

Rights and permissions

Reprints and permissions

About this article

Cite this article

Mazheika, I.B., Chipen, G.I. & Hiller, S.A. Electron density distribution in heterocyclic systems with two adjacent nitrogen atoms. Chem Heterocycl Compd 2, 600–605 (1966). https://doi.org/10.1007/BF00477530

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00477530

Keywords

Search

Navigation