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Heterocyclic analogs of pleiadiene

48. Pyrosulfite as a mild dehydrogenating agent in the 2,3-dihydroperimidine series. Synthesis of 2-polyhydroxyalkylperimidines

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

2,3-Dihydroperimidines are dehydrogenated smoothly by sodium pyrosulfite in refluxing aqueous alcohol, as a result of which the corresponding perimidines are formed in high yields. The reaction of 1,8-naphthalenediamine with the aldehydic forms of sugars gives 2-polyhydroxyalkyl-2,3-dihydroperimidines, which are also aromatized by sodium pyrosulfite to give the corresponding 2-polyhydroxyalkyl-perimidines in high yields.

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Authors and Affiliations

  1. Rostov State University, 344006, Rostov-on-Don

    N. M. Starshikov & A. F. Pozharskii

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  1. N. M. Starshikov
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  2. A. F. Pozharskii
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Additional information

See [1] for Communication 47.

Translated from Khimiya Geterotsikliches-kikh Soedinenii, No. 1, pp. 96–100, January, 1980.

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Starshikov, N.M., Pozharskii, A.F. Heterocyclic analogs of pleiadiene. Chem Heterocycl Compd 16, 81–85 (1980). https://doi.org/10.1007/BF00475399

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  • DOI: https://doi.org/10.1007/BF00475399

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